Labrador Sea bottom water provenance and REE exchange during the past 35,000 years ...

Deep waters of the Labrador Sea (LS) are important contributors to the Atlantic Meridional Overturning Circulation, but their water mass structure has been highly variable and sensitive to climatic changes on different time scales. The LS is also an area of intense exchange of rare earth elements (R...

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Bibliographic Details
Main Authors: Blaser, Patrick, Gutjahr, Marcus, Pöppelmeier, Frerk, Frank, Martin, Kaboth-Bahr, Stefanie, Lippold, Jörg
Format: Text
Language:unknown
Published: Elsevier 2020
Subjects:
Online Access:https://dx.doi.org/10.48350/158655
https://boris.unibe.ch/158655/
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Summary:Deep waters of the Labrador Sea (LS) are important contributors to the Atlantic Meridional Overturning Circulation, but their water mass structure has been highly variable and sensitive to climatic changes on different time scales. The LS is also an area of intense exchange of rare earth elements (REE) between seawater and the underlying sediments, which complicates the reconstruction of past deep water provenance based on radiogenic neodymium (Nd) isotopes. Most notably, Northwest Atlantic Bottom Water exchanges Nd with Archaean age Laurentian detritus, resulting in a significant shift to less radiogenic Nd isotope signatures before it enters the North Atlantic to form the deep part of North Atlantic Deep Water. Here we show that the authigenic fractions of LS core top sediments carry Nd isotope signatures intermediate between bottom water and detritus and thus reflect pore waters that incorporate a mixture of both signatures. We furthermore find that detrital imprints on pore waters led to shifts of REE ...