Compound‐Specific Radiocarbon Analysis of (Sub‐)Antarctic Coastal Marine Sediments—Potential and Challenges for Chronologies ...

In Antarctic and Subantarctic environments, 14C‐based age determination is often challenging due to unknown reservoir effects, low organic carbon contents of sediments, and high contributions of petrogenic (14C‐free) carbon in ice marginal settings. In this study, we evaluate possible benefits and c...

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Bibliographic Details
Main Authors: Berg, Sonja, Jivcov, Sandra, Kusch, Stephanie, Kuhn, Gerhard, Wacker, Lukas, Rethemeyer, Janet
Format: Article in Journal/Newspaper
Language:English
Published: ETH Zurich 2020
Subjects:
Online Access:https://dx.doi.org/10.3929/ethz-b-000448962
http://hdl.handle.net/20.500.11850/448962
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Summary:In Antarctic and Subantarctic environments, 14C‐based age determination is often challenging due to unknown reservoir effects, low organic carbon contents of sediments, and high contributions of petrogenic (14C‐free) carbon in ice marginal settings. In this study, we evaluate possible benefits and challenges of compound‐specific radiocarbon analysis (CSRA) as a tool for age determination of marine Antarctic and Subantarctic sediment sequences. We present a comprehensive data set of 14C ages obtained on bulk organic carbon, carbonates, and on fatty acids (FA) from three coastal marine sediment cores from Subantarctic South Georgia and East Antarctica. Low molecular weight (LMW) FA represent the least 14C‐depleted fraction, indicating that the phytoplankton‐derived compounds can be a means of dating sediments. In contrast, vascular plant‐derived high molecular weight FA are systematically depleted in 14C relative to the low molecular weight homologues, reflecting processes such as soil formation/erosion in the ... : Paleoceanography and Paleoclimatology, 35 (10) ...