Atmospheric methane variability: Centennial-scale signals in the Last Glacial Period ...

In order to understand atmospheric methane (CH$_{4}$) biogeochemistry now and in the future, we must apprehend its natural variability, without anthropogenic influence. Samples of ancient air trapped within ice cores provide the means to do this. Here we analyze the ultrahigh-resolution CH$_{4}$ rec...

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Bibliographic Details
Main Authors: Rhodes, RH, Brook, EJ, McConnell, Blunier, T, Sime, LC, Faïn, X, Mulvaney, R
Format: Article in Journal/Newspaper
Language:English
Published: Wiley 2017
Subjects:
Online Access:https://dx.doi.org/10.17863/cam.9897
https://www.repository.cam.ac.uk/handle/1810/264411
Description
Summary:In order to understand atmospheric methane (CH$_{4}$) biogeochemistry now and in the future, we must apprehend its natural variability, without anthropogenic influence. Samples of ancient air trapped within ice cores provide the means to do this. Here we analyze the ultrahigh-resolution CH$_{4}$ record of the West Antarctic Ice Sheet Divide ice core 67.2–9.8 ka and find novel, atmospheric CH$_{4}$ variability at centennial time scales throughout the record. This signal is characterized by recurrence intervals within a broad 80–500 year range, but we find that age-scale uncertainties complicate the possible isolation of any periodic frequency. Lower signal amplitudes in the Last Glacial relative to the Holocene may be related to incongruent effects of firn-based signal smoothing processes. Within interstadial and stadial periods, the peak-to-peak signal amplitudes vary in proportion to the underlying millennial-scale oscillations in CH$_{4}$ concentration—the relative amplitude change is constant. We propose ...