The efficacy of enhancing carbonate weathering for carbon dioxide sequestration ...

Enhanced weathering is a geoengineering strategy aiming to increase continental weathering rates, thereby increasing the delivery of atmospheric carbon (as HCO3-) to the oceans. Most enhanced weathering studies focus on the capacity of silicate rocks (e.g., basalt) and minerals (e.g., olivine, Mg 2...

Full description

Bibliographic Details
Main Authors: Knapp, William J, Tipper, Edward T
Format: Article in Journal/Newspaper
Language:English
Published: Frontiers Media SA 2022
Subjects:
Online Access:https://dx.doi.org/10.17863/cam.87869
https://www.repository.cam.ac.uk/handle/1810/340432
Description
Summary:Enhanced weathering is a geoengineering strategy aiming to increase continental weathering rates, thereby increasing the delivery of atmospheric carbon (as HCO3-) to the oceans. Most enhanced weathering studies focus on the capacity of silicate rocks (e.g., basalt) and minerals (e.g., olivine, Mg 2 SiO 4 , or wollastonite CaSiO 3 ) to remove atmospheric CO 2 . However, carbonate minerals (e.g., calcite, CaCO 3 ) could provide an additional, rapid way to increase HCO3- export to the oceans. Recent studies suggest that 0.84 Gt C yr −1 could be removed from the atmosphere through the enhanced dissolution of calcite in soils, provided carbonic acid is the main dissolution agent. What is not clear is whether atmospheric CO 2 dissolved in soils can be transported by rivers, which typically have lower [pCO 2 ], to the oceans. This difference in calcite solubility between soils (where weathering occurs) and rivers (where HCO3- is transported) may lead to large amounts of secondary carbonate formation during ...