(Table 1) Annual mean concentrations of atmospheric a- and g-Hexachlorocyclohexane at stations Alert, Canada and Zeppelin, Norway, supplement to: Becker, Sara; Halsall, Crispin J; Tych, Wlodek; Kallenborn, Roland; Su, Yushan; Hung, Hayley (2008): Long-term trends in atmospheric concentrations of a- and g-HCH in the Arctic provide insight into the effects of legislation and climatic fluctuations on contaminant levels. Atmospheric Environment, 42(35), 8225-8233

• Main Authors: Becker, Sara, Halsall, Crispin J, Tych, Wlodek, Kallenborn, Roland, Su, Yushan, Hung, Hayley
• Format: Dataset
• Language: English
• Published: PANGAEA - Data Publisher for Earth & Environmental Science 2008
• Subjects: ipy; Event label; Latitude of event; Longitude of event; DATE/TIME; Sample amount; alpha-Hexachlorocyclohexane in air; Hexachlorocyclohexane, standard deviation; gamma-Hexachlorocyclohexane in air; Ratio; Observation; Air chemistry observatory; Joint Arctic Weather Stations; International Polar Year 2007-2008 IPY; Arctic; Canada; Norway; Nunavut; Roland; Svalbard; International Polar Year; IPY
• Online Access: https://dx.doi.org/10.1594/pangaea.786649; https://doi.pangaea.de/10.1594/PANGAEA.786649

Twelve year datasets of weekly atmospheric concentrations of alpha- and gamma-HCH were compared between the two Arctic monitoring stations of Alert, Nunavut, Canada, and Zeppelin Mountain, Svalbard, Norway. Time-series analysis was conducted with the use of dynamic harmonic regression (DHR), which provided a very good model fit, to examine both the seasonal behaviour in these isomers and the longer-term, underlying trends. Strong spatial differences were not apparent between the two sites, although subtle differences in seasonal behaviour and composition were identified. For example, the composition of gamma-HCH to total HCH (alpha + gamma) was greater at Zeppelin compared to Alert, probably reflecting this site's proximity to major use regions of lindane. Pronounced seasonality in air concentrations for gamma-HCH was marked by a 'spring maximum event' (SME), confirming earlier studies. For alpha-HCH, the SME was much weaker and only evident at Alert, whereas at Zeppelin, seasonal fluctuations for alpha-HCH were marked by elevated concentrations in summer and lower concentrations during winter, with this pattern most apparent for the years after 2000. We attribute this difference in spatial and temporal patterns to the Arctic oscillation. A similar climatic pattern was not evident at either site in the gamma-HCH data. Seasonally adjusted, long-term trends revealed declining concentrations at both sites for alpha- and gamma-HCH over the entire time-series. Recent legislation affecting lindane use appear to account for this decline in gamma-HCH, with little evidence of a delay or 'lag' between the banning of lindane in Europe (a main source region) or Canada, and a decline in air concentrations observed at both Arctic sites. : Data extracted in the frame of a joint ICSTI/PANGAEA IPY effort, see http://doi.pangaea.de/10.1594/PANGAEA.150150