(Table 1) Boron-isotope measurements of shallow-dwelling planktonic foraminifera of ODP Holes 144-817A, 144-872C and 143-865C, supplement to: Pearson, Paul N; Palmer, Martin R (2000): Atmospheric carbon dioxide concentrations over the past 60 million years. Nature, 406, 695-699

Knowledge of the evolution of atmospheric carbon dioxide concentrations throughout the Earth's history is important for a reconstruction of the links between climate and radiative forcing of the Earth's surface temperatures. Although atmospheric carbon dioxide concentrations in the early C...

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Bibliographic Details
Main Authors: Pearson, Paul N, Palmer, Martin R
Format: Dataset
Language:English
Published: PANGAEA - Data Publisher for Earth & Environmental Science 2000
Subjects:
AGE
pH
Online Access:https://dx.doi.org/10.1594/pangaea.769843
https://doi.pangaea.de/10.1594/PANGAEA.769843
Description
Summary:Knowledge of the evolution of atmospheric carbon dioxide concentrations throughout the Earth's history is important for a reconstruction of the links between climate and radiative forcing of the Earth's surface temperatures. Although atmospheric carbon dioxide concentrations in the early Cenozoic era (about 60 Myr ago) are widely believed to have been higher than at present, there is disagreement regarding the exact carbon dioxide levels, the timing of the decline and the mechanisms that are most important for the control of CO2 concentrations over geological timescales. Here we use the boron-isotope ratios of ancient planktonic foraminifer shells to estimate the pH of surface-layer sea water throughout the past 60 million years, which can be used to reconstruct atmospheric CO2 concentrations. We estimate CO2 concentrations of more than 2,000 p.p.m. for the late Palaeocene and earliest Eocene periods (from about 60 to 52 Myr ago), and find an erratic decline between 55 and 40 Myr ago that may have been caused by reduced CO2 outgassing from ocean ridges, volcanoes and metamorphic belts and increased carbon burial. Since the early Miocene (about 24 Myr ago), atmospheric CO2 concentrations appear to have remained below 500 p.p.m. and were more stable than before, although transient intervals of CO2 reduction may have occurred during periods of rapid cooling approximately 15 and 3 Myr ago. : The ages of each sample were calculated by linear interpolation between reliable biostratigraphical datums for Sites 871 and 872 (as determined by Pearson, 1995) and for Site 865 (R. D. Norris & H. Nishi, unpublished data). Samples consisting of various species are the means of analyses presented in previous studies (Palmer et al., 1998 dataset: doi:10.1594/PANGAEA.769846; Pearson and Palmer, 1999 dataset: doi:10.1594/PANGAEA.769847). Hantkenina alabamensis samples were exluded from subsequent geochemical calculations because they probably represent vital-effect fractionation of the boron isotopes. The d11Bsw value for each sample is calculated from the d11Bsw differential from surface to oxygen minimum zone at discrete levels, or interpolation between those levels following the method of Pearson and Palmer (1999).