Speciation of metals in bottom sediments from the south Kara Sea and Ob and Yenisei estuarine zones ...

Speciation of Fe, Mn, Zn, Cu, Co, Ni, Cr, Pb, and Cd was studied in 52 samples of bottom sediments collected during Cruise 49 of the R/V "Dmitry Mendeleev" to the estuaries of the Ob and Yenisei rivers and to the southwest Kara Sea. Immediately after sampling the samples were subjected to...

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Bibliographic Details
Main Authors: Demina, Lyudmila L, Levitan, Mikhail A, Politova, Nadezhda V
Format: Article in Journal/Newspaper
Language:English
Published: PANGAEA 2006
Subjects:
Online Access:https://dx.doi.org/10.1594/pangaea.725841
https://doi.pangaea.de/10.1594/PANGAEA.725841
Description
Summary:Speciation of Fe, Mn, Zn, Cu, Co, Ni, Cr, Pb, and Cd was studied in 52 samples of bottom sediments collected during Cruise 49 of the R/V "Dmitry Mendeleev" to the estuaries of the Ob and Yenisei rivers and to the southwest Kara Sea. Immediately after sampling the samples were subjected to on-board consecutive extraction to separate metal species according to their modes of occurrence in the sediments: (1) adsorbed, (2) amorphous Fe-Mn hydroxides and related metals, (3) organic + sulfide, and (4) residual, or lithogenic. Atomic absorption spectroscopy of the extracts was carried out at a stationary laboratory. Distribution of Fe, Zn, Cu, Co, Ni, Cr, Pb, and Cd species is characterized by predominance of lithogenic or geochemically inert modes (70-95% of bulk contents), in which the metals are bound in terrigenous and clastic mineral particles and organic detritus. About half of total Mn amount and 15-30% of Zn and Cu are contained in geochemically mobile modes. Spatiotemporal variations in proportions of the ... : Supplement to: Demina, Lyudmila L; Levitan, Mikhail A; Politova, Nadezhda V (2006): Speciation of some heavy metals in bottom sediments of the Ob and Yenisei estuarine zones. Geochemistry International, 44(2), 182-195 ...