Chemical composition of sediments at DSDP Site 72-516 ...

Sediment samples (32) from DSDP Holes 516 and 516F, Leg 72 were subjected to INAA (instrumental neutron activation analysis). Thirty-two major, minor and trace elements were determined. Ce anomalies, Ce_a = Ce (obs.)/Ce* (interpolated between La and Nd and relative to the NASC (North American Shale...

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Bibliographic Details
Main Authors: Hu, X, Wang, Yan-Long, Schmitt, Roman A
Format: Article in Journal/Newspaper
Language:English
Published: PANGAEA 1988
Subjects:
Online Access:https://dx.doi.org/10.1594/pangaea.707379
https://doi.pangaea.de/10.1594/PANGAEA.707379
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Summary:Sediment samples (32) from DSDP Holes 516 and 516F, Leg 72 were subjected to INAA (instrumental neutron activation analysis). Thirty-two major, minor and trace elements were determined. Ce anomalies, Ce_a = Ce (obs.)/Ce* (interpolated between La and Nd and relative to the NASC (North American Shale Composite)) = Ce (obs.)/[1.44 La (obs.) + 0.66 Nd (obs.)], in the carbonate phase were obtained. Calculations indicate that the Ce anomaly changed from 0.80 (80 My), 0.68 (67 My) to 0.30 (56 My), 0.27 (39 My) and 0.12–0.43 (avg. 0.26) (15?0.3 My). The Ce anomaly change observed at ~55 My coincides with the Ce anomaly change at ~58 My in marine carbonates from the Walvis Ridge, Hole 525A. These changes are attributed to improved water circulation caused by either the widening of the north-south Atlantic passage, subsidence of the Rio Grande Rise or subsidence of the Romanche Fracture Zone. The ultimate driving force behind the Ce anomaly changes is related to the pH and pO2 of the seawater and also related to ... : Supplement to: Hu, X; Wang, Yan-Long; Schmitt, Roman A (1988): Geochemistry of sediments on the Rio Grande Rise and the redox evolution of the South Atlantic Ocean. Geochimica et Cosmochimica Acta, 52(1), 201-207 ...