Influence of basement rocks on fluid evolution during multiphase deformation: The example of the Estamariu thrust in the Pyrenean Axial Zone

Calcite veins precipitated in the Estamariu thrust during two tectonic events are studied in order to (i) decipher the temporal and spatial relationships between deformation and fluid migration in a long-lived thrust and (ii) determine the influence of basement rocks on the fluid chemistry during de...

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Bibliographic Details
Published in:Solid Earth
Main Authors: Muñoz-López, D., Alías, G., Cruset, David, Cantarero, I., John, Cédric M., Travé, A.
Other Authors: Ministerio de Ciencia, Innovación y Universidades (España), Ministerio de Economía y Competitividad (España)
Format: Article in Journal/Newspaper
Language:English
Published: European Geosciences Union 2020
Subjects:
DML
Online Access:http://hdl.handle.net/10261/224472
https://doi.org/10.5194/se-11-2257-2020
https://doi.org/10.13039/501100003329
Description
Summary:Calcite veins precipitated in the Estamariu thrust during two tectonic events are studied in order to (i) decipher the temporal and spatial relationships between deformation and fluid migration in a long-lived thrust and (ii) determine the influence of basement rocks on the fluid chemistry during deformation. Structural and petrological observations constrain the relative timing of fluid migration and vein formation, whilst geochemical analyses (13C, 18O, 87Sr=86Sr, clumped isotope thermometry, and elemental composition) applied to the related calcite cements and host rocks indicate the fluid origin, pathways, and extent of fluid rock interaction. The first tectonic event, recorded by calcite cements Cc1a and Cc2, is attributed to the Alpine reactivation of the Estamariu thrust. Analytical data indicate that these cements precipitated from heated meteoric fluids (temperatures in the range of 50 to 100 C) that had interacted with basement rocks (87Sr=86Sr 0.71) before upflowing through the thrust zone. The second tectonic event, attributed to the Neogene extension, is characterized by the reactivation of the Estamariu thrust and the formation of normal faults and shear fractures sealed by calcite cements Cc3, Cc4, and Cc5. Analytical data indicate that cements Cc3 and Cc4 precipitated from hydrothermal fluids (temperatures between 130 and 210 C and between 100 and 170 C, respectively) that had interacted with basement rocks (87Sr=86Sr 0.71) and been expelled through fault zones during deformation. In contrast, cement Cc5 probably precipitated from meteoric waters that likely percolated from the surface through small shear fractures. The comparison between our results and already published data in other structures from the southern Pyrenees suggests that regardless of the origin of the fluids and the tectonic context, basement rocks have a significant influence on the fluid chemistry, particularly on the 87Sr=86Sr ratio. Accordingly, the cements precipitated from fluids that have interacted with basement rocks have significantly higher 87Sr=86Sr ratios (0.710) with respect to those precipitated from fluids that have interacted with the sedimentary cover (0.710), which involves younger and less radiogenic rocks. © 2020 Copernicus GmbH. All rights reserved. This research was carried out within the framework of the DGICYT Spanish project PGC2018-093903-B-C22 (Ministerio de Ciencia, Innovación y Universidades/Agencia Estatal de Investigación/Fondo Europeo de Desarrollo Regional, Unión Europea) and the Grup Consolidat de Recerca “Geologia Sedimentària” (2017-SGR-824). The PhD research of DML is supported by the FPI2016 (BES-2016-077214) Spanish program from MINECO. Peer reviewed