Proxies and measurement techinques for mineral dust in antarctic ice cores

To improve quantitative interpretation of ice core aeolian dust records, a systematic methodological comparison was made. This involved methods for water-insoluble particle counting (Coulter counter and laser-sensing particle detector), soluble ion analysis (ion chromatography and continuous flow an...

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Bibliographic Details
Published in:Environmental Science & Technology
Main Authors: Ruth. , Urs, Bigler, Matthias
Format: Article in Journal/Newspaper
Language:English
Published: 2008
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Online Access:https://curis.ku.dk/portal/da/publications/proxies-and-measurement-techinques-for-mineral-dust-in-antarctic-ice-cores(21d096a0-f83b-11dd-b219-000ea68e967b).html
https://doi.org/10.1021/es703078z
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Summary:To improve quantitative interpretation of ice core aeolian dust records, a systematic methodological comparison was made. This involved methods for water-insoluble particle counting (Coulter counter and laser-sensing particle detector), soluble ion analysis (ion chromatography and continuous flow analysis), elemental analysis (inductively coupled plasma mass spectroscopy at pH 1 and after full acid digestion), and water-insoluble elemental analysis (proton induced X-ray emission). Antarctic ice core samples covering the last deglaciation from the EPICA Dome C (EDC) and the EPICA Dronning Maud Land (EDML) cores were used. All methods correlate very well among each other, but the ratios of glacial age to Holocene concentrations, which are typically a factor 100, differ between the methods by up to a factor of 2 with insoluble particles showing the largest variability. The recovery of ICP-MS measurements depends on the digestion method and is different for different elements and during different climatic periods. EDC and EDML samples have similar dust composition, which suggests a common dust source or a common mixture of sources for the two sites. The analyzed samples further reveal a change of dust composition during the last deglaciation. Udgivelsesdato: 2 July