SARAH-JANE BARNES§

The Pechenga Ni-sulfide deposits, in the Kola Peninsula of Russia, are associated with ferropicrite flows and intrusions. The sulfides are divided into five types: 1) disseminated sulfides within the olivine cumulate portions of the ferropicrites, 2) massive sulfides, which occur at the contact betw...

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Bibliographic Details
Main Authors: Victor A. Melezhik, Stanislav V. Sokolov
Other Authors: The Pennsylvania State University CiteSeerX Archives
Format: Text
Language:English
Subjects:
Online Access:http://citeseerx.ist.psu.edu/viewdoc/summary?doi=10.1.1.537.3546
http://rruff.info/doclib/cm/vol39/CM39_447.pdf
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Summary:The Pechenga Ni-sulfide deposits, in the Kola Peninsula of Russia, are associated with ferropicrite flows and intrusions. The sulfides are divided into five types: 1) disseminated sulfides within the olivine cumulate portions of the ferropicrites, 2) massive sulfides, which occur at the contact between the ferropicrites and the country-rock black schists, 3) breccia-matrix sulfides, which occur at the contact between the ferropicrites and the schists, and in some cases continue for hundreds of meters subparallel to the contact but within the footwall, 4) chalcopyrite vein or stringer sulfides, which occur in the footwall, and 5) pyrite-rich layers, concretions and lenses in the sedimentary rocks. The disseminated sulfides have similarly shaped mantle-normalized patterns of chalcophile metal abundances to those of the ferropicrites, and could have formed in equilibrium with the ferropicritic magma at moderate R factors (250). The rocks are depleted in platinum-group elements (PGE), suggesting that the magma reached sulfide saturation prior to the formation of the ores. Sulfur isotope data indicate that the S was derived from the sediments onto and into which the ferropicrites were emplaced. The high As and Sb concentrations in the sulfides may have been derived from the sediments. The massive sulfides show a wider variety of composition than the disseminated sulfides; some sulfides are enriched in Os, Ir, Ru, Rh and depleted Pt, Pd, Ag, Au, Cu, Sb, As, Se. This pattern is attributed to the accumulation of monosulfide solid-solution during crystallization of a sulfide liquid. The sedimentary sulfides are richer in As and Sb than the disseminated and massive sulfides, but poorer in all the other chalcophile elements. The breccia-matrix sulfides consist of sedimentary and