Atmospheric Chemistry and Physics Factors controlling Arctic denitrification in cold winters of the 1990s
Abstract. Denitrification of the Arctic winter stratosphere has been calculated using a 3-D microphysical model for the winters 1994/95, 1995/96, 1996/97 and 1999/2000. Denitrification is assumed to occur through the sedimentation of low number concentrations of large nitric acid trihydrate (NAT) pa...
| Main Authors: | , , |
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| Other Authors: | |
| Format: | Text |
| Language: | English |
| Published: |
2003
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| Subjects: | |
| Online Access: | http://citeseerx.ist.psu.edu/viewdoc/summary?doi=10.1.1.404.8490 http://hal.archives-ouvertes.fr/docs/00/29/52/49/PDF/acp-3-403-2003.pdf |
| Summary: | Abstract. Denitrification of the Arctic winter stratosphere has been calculated using a 3-D microphysical model for the winters 1994/95, 1995/96, 1996/97 and 1999/2000. Denitrification is assumed to occur through the sedimentation of low number concentrations of large nitric acid trihydrate (NAT) particles (as inferred by e.g. Fahey et al., 2001). We examine whether the meteorological conditions that allowed particles to grow to the very large sizes observed in 1999/2000 also occurred in the other cold winters. The results show that winter 1999/2000 had conditions that were optimum for denitrification by large NAT particles, which are a deep concentric NAT area and vortex. Under these conditions, NAT particles can circulate in the NAT-supersaturated air for several days, reaching several micrometres in radius and leading to a high downward flux of nitric acid. The other winters |
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