stoichiometry of mixed layer export
Abstract. Sinking particles, once caught in sediment trap jars, release dissolved elements into the surrounding medium through leaching from their pore fluids, chemical dissolution and the activity of free exoenzymes. This results in an increase in dissolved elements in the trap jar supernatant. Ele...
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| Format: | Text |
| Language: | English |
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2005
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| Online Access: | http://citeseerx.ist.psu.edu/viewdoc/summary?doi=10.1.1.391.2757 http://hal.archives-ouvertes.fr/docs/00/29/75/21/PDF/bg-2-189-2005.pdf |
| Summary: | Abstract. Sinking particles, once caught in sediment trap jars, release dissolved elements into the surrounding medium through leaching from their pore fluids, chemical dissolution and the activity of free exoenzymes. This results in an increase in dissolved elements in the trap jar supernatant. Elemental fluxes as traditionally measured by sediment traps underestimate total export when this particle-associated dissolved flux is not considered. The errors introduced are variable and alter both the absolute levels of flux as well as the stoichiometry of export. These errors have been quantified and corrections applied for samples from sediment traps in the North Atlantic based on measurements of excess dissolved carbon, nitrogen, phosphorus, silica and calcium in the supernatant of the collection cups. At the base of the winter mixed layer, on average 90±6 % of phosphorus fluxes |
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