Initial Phases of Antarctic Ramalina terebrata Hook f. & Taylor Thalli Rehydration Observed by Proton Relaxometry

Hydration kinetics, sorption isotherm, and proton free induction decays are measured for Ramalina terebrata thalli rehydrated from gaseous phase. Very tightly, tightly, and loosely bound water fractions are distinguished. Sorption isotherm is sigmoidal in form with the mass of water saturating prima...

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Bibliographic Details
Main Authors: H Harańczyk, Ł Pater, P Nowak, M Bacior, M A Olech
Other Authors: The Pennsylvania State University CiteSeerX Archives
Format: Text
Language:English
Published: 2012
Subjects:
Online Access:http://citeseerx.ist.psu.edu/viewdoc/summary?doi=10.1.1.1085.4137
http://przyrbwn.icm.edu.pl/APP/PDF/121/a121z2p68.pdf
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Summary:Hydration kinetics, sorption isotherm, and proton free induction decays are measured for Ramalina terebrata thalli rehydrated from gaseous phase. Very tightly, tightly, and loosely bound water fractions are distinguished. Sorption isotherm is sigmoidal in form with the mass of water saturating primary water binding sites equal to ∆m/m 0 = 0.046. Proton free induction decays show the presence of immobilized water fraction (T * 2L 1 ≈ 100 µs) and mobile water pool (T * 2L 2 ≈ 330 µs). Sorption isotherm fitted to the NMR data shows the absence of water fraction "sealed" in pores of dry thallus.