Daily variability of dissolved inorganic radiocarbon at three sites in the surface ocean

We report radiocarbon measurements of dissolved inorganic carbon (DIC) in surface water samples collected daily during cruises to the central North Pacific, the Sargasso Sea and the Southern Ocean. The ranges of Δ14C measurements for each cruise (11-30‰) were larger than the total uncertainty (7.8‰,...

Full description

Bibliographic Details
Main Authors: Druffel, ERM, Griffin, S
Format: Article in Journal/Newspaper
Language:unknown
Published: eScholarship, University of California 2008
Subjects:
Online Access:https://escholarship.org/uc/item/8f58352t
Description
Summary:We report radiocarbon measurements of dissolved inorganic carbon (DIC) in surface water samples collected daily during cruises to the central North Pacific, the Sargasso Sea and the Southern Ocean. The ranges of Δ14C measurements for each cruise (11-30‰) were larger than the total uncertainty (7.8‰, 2-sigma) of the measurements. The variability is attributed to changes in the upper water mass that took place at each site over a two to four week period. These results indicate that variability of surface Δ14C values is larger than the analytical precision, because of patchiness that exists in the DIC Δ14C signature of the surface ocean. This additional variability can affect estimates of geochemical parameters such as the air-sea CO2 exchange rate using radiocarbon. © 2008 Elsevier B.V. All rights reserved.