Dynamic recycling of gaseous elemental mercury in the boundary layer of the Antarctic Plateau

• Published in: Atmospheric Chemistry and Physics
• Main Authors: Dommergue, A., Barret, M., Courteaud, J., Cristofanelli, P., Ferrari, C. P., Gallée, H.
• Other Authors: Laboratoire de glaciologie et géophysique de l'environnement (LGGE), Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire des Sciences de l'Univers de Grenoble (OSUG), Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national des sciences de l'Univers (INSU - CNRS)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB Université de Savoie Université de Chambéry )-Centre National de la Recherche Scientifique (CNRS)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB Université de Savoie Université de Chambéry )-Centre National de la Recherche Scientifique (CNRS), CNR Institute of Atmospheric Sciences and Climate (ISAC), Consiglio Nazionale delle Ricerche (CNR)
• Format: Article in Journal/Newspaper
• Language: English
• Published: HAL CCSD 2012
• Subjects: [SDU.STU]Sciences of the Universe [physics]/Earth Sciences; Antarctic; Arctic; Concordia Station; The Antarctic; Antarc*
• Online Access: https://hal-insu.archives-ouvertes.fr/insu-00843620; https://hal-insu.archives-ouvertes.fr/insu-00843620/document; https://hal-insu.archives-ouvertes.fr/insu-00843620/file/acp-12-11027-2012.pdf; https://doi.org/10.5194/acp-12-11027-2012

International audience Gaseous elemental mercury (Hg0) was investigated in the troposphere and in the interstitial air extracted from the snow at Dome Concordia station (alt. 3320 m) on the Antarctic Plateau during January 2009. Measurements and modeling studies showed evidence of a very dynamic and daily cycling of Hg0 inside the mixing layer with a range of values from 0.2 ng m−3 up to 2.3 ng m−3. During low solar irradiation periods, fast Hg0 oxidation processes in a confined layer were suspected. Unexpectedly high Hg0 concentrations for such a remote place were measured under higher solar irradiation due to snow photochemistry. We suggest that a daily cycling of reemission/oxidation occurs during summer within the mixing layer at Dome Concordia. Hg0 concentrations showed a negative correlation with ozone mixing ratios, which contrasts with atmospheric mer- cury depletion events observed during the Arctic spring. Un- like previous Antarctic studies, we think that atmospheric Hg0 removal may not be the result of advection processes. The daily and dramatic Hg0 losses could be a consequence of surface or snow induced oxidation pathways. It remains however unclear whether halogens are involved. The cycling of other oxidants should be investigated together with Hg species in order to clarify the complex reactivity on the Antarctic plateau.