Synthesis, structure and magnetic properties of a series of Ln( iii ) complexes with radical-anionic iminopyridine ligands: effect of lanthanide ions on the slow relaxation of the magnetization
International audience We report the investigation of synthesis, structure and magnetic properties of a series of homoleptic Ln(III) complexes coordinated by radical-anionic iminopyridine ligands of general formula [Ln(IPy)3]·solv (IPy = iminopyridine; Ln = Tb, Dy, Er, Y, Gd). The dysprosium analogu...
Published in: | Dalton Transactions |
---|---|
Main Authors: | , , , , , , , |
Other Authors: | , , , , |
Format: | Article in Journal/Newspaper |
Language: | English |
Published: |
HAL CCSD
2019
|
Subjects: | |
Online Access: | https://hal.archives-ouvertes.fr/hal-02270823 https://hal.archives-ouvertes.fr/hal-02270823/document https://hal.archives-ouvertes.fr/hal-02270823/file/preprint.pdf https://doi.org/10.1039/C9DT00738E |
Summary: | International audience We report the investigation of synthesis, structure and magnetic properties of a series of homoleptic Ln(III) complexes coordinated by radical-anionic iminopyridine ligands of general formula [Ln(IPy)3]·solv (IPy = iminopyridine; Ln = Tb, Dy, Er, Y, Gd). The dysprosium analogue exhibits a zero-field Single-Molecule Magnet (SMM) behavior. |
---|