Influence of the water content in the synthesis of fructose laurate by immobilized lipase B of Candida antarctica (Novozym 435)
International audience New synthesis conditions for a direct esterification of fructose by lauric acid with Novozym 435 as a catalyst are reported in this paper. With these new conditions, a conversion rate of 72 % was achieved, which is almost the same value as in the case of transesterification wh...
Main Authors: | , , |
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Other Authors: | , , , , , , , |
Format: | Article in Journal/Newspaper |
Language: | English |
Published: |
HAL CCSD
2012
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Subjects: | |
Online Access: | https://hal.science/hal-00688332 https://hal.science/hal-00688332/document https://hal.science/hal-00688332/file/bsrsl_1.pdf |
Summary: | International audience New synthesis conditions for a direct esterification of fructose by lauric acid with Novozym 435 as a catalyst are reported in this paper. With these new conditions, a conversion rate of 72 % was achieved, which is almost the same value as in the case of transesterification where no water as by-product is produced (74.6 %). The conversion rate of these reactions can be modeled as a function of the initial water content by a three-parameter power law for the esterification and by an exponential law for the transesterification. The influence of the water content on the mono over di-ester ratio will also be discussed to a lesser extent. |
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