Rheological characterization and modelling of hydrates slurries during crystallization under laminar flowing
10 pages An original experimental set-up was developed and used for studying crystallization and rheology of methane hydrate/water/dodecane system under laminar flowing. Dynamic viscosity and conversion of water and gas into gas hydrate crystals were measured during the process for various water con...
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ftccsdartic:oai:HAL:hal-00125062v1 2023-05-15T17:11:57+02:00 Rheological characterization and modelling of hydrates slurries during crystallization under laminar flowing FIDEL-DUFOUR, Annie Gruy, Frédéric Herri, Jean-Michel Centre Sciences des Processus Industriels et Naturels (SPIN-ENSMSE) École des Mines de Saint-Étienne (Mines Saint-Étienne MSE) Institut Mines-Télécom Paris (IMT)-Institut Mines-Télécom Paris (IMT) Département Géochimie, environnement, écoulement, réacteurs industriels et cristallisation (GENERIC-ENSMSE) Institut Mines-Télécom Paris (IMT)-Institut Mines-Télécom Paris (IMT)-SPIN Laboratoire des Procédés en Milieux Granulaires (LPMG-EMSE) Institut Mines-Télécom Paris (IMT)-Institut Mines-Télécom Paris (IMT)-Centre National de la Recherche Scientifique (CNRS) Tromdheim, Norway 2005-06-13 https://hal.archives-ouvertes.fr/hal-00125062 https://hal.archives-ouvertes.fr/hal-00125062/document https://hal.archives-ouvertes.fr/hal-00125062/file/ICHG5-AFD.pdf en eng HAL CCSD hal-00125062 https://hal.archives-ouvertes.fr/hal-00125062 https://hal.archives-ouvertes.fr/hal-00125062/document https://hal.archives-ouvertes.fr/hal-00125062/file/ICHG5-AFD.pdf info:eu-repo/semantics/OpenAccess Fifth International Conference on Gas Hydrates (ICGH 5), Norvège, 13 au 16 juin 2005 https://hal.archives-ouvertes.fr/hal-00125062 Fifth International Conference on Gas Hydrates (ICGH 5), Norvège, 13 au 16 juin 2005, Jun 2005, Tromdheim, Norway rheology cristallisation agglomeration laminar flowing [SPI.OTHER]Engineering Sciences [physics]/Other info:eu-repo/semantics/conferenceObject Conference papers 2005 ftccsdartic 2020-12-26T18:48:48Z 10 pages An original experimental set-up was developed and used for studying crystallization and rheology of methane hydrate/water/dodecane system under laminar flowing. Dynamic viscosity and conversion of water and gas into gas hydrate crystals were measured during the process for various water contents. Experimental results were explained by means of a model including nucleation, growth and agglomeration. Due to the high value of crystal and drop concentrations, agglomeration takes place through three-bodies collisions between one water drop and two already formed agglomerates. Resulting agglomerates were considered as fractal-like ones. During crystallization and agglomeration, the effective volume fraction of drops and porous agglomerates is increased, then suspension viscosity increases. When all water drops are crystallized, agglomeration stops and viscosity do not change. Conference Object Methane hydrate Archive ouverte HAL (Hyper Article en Ligne, CCSD - Centre pour la Communication Scientifique Directe) Norway |
institution |
Open Polar |
collection |
Archive ouverte HAL (Hyper Article en Ligne, CCSD - Centre pour la Communication Scientifique Directe) |
op_collection_id |
ftccsdartic |
language |
English |
topic |
rheology cristallisation agglomeration laminar flowing [SPI.OTHER]Engineering Sciences [physics]/Other |
spellingShingle |
rheology cristallisation agglomeration laminar flowing [SPI.OTHER]Engineering Sciences [physics]/Other FIDEL-DUFOUR, Annie Gruy, Frédéric Herri, Jean-Michel Rheological characterization and modelling of hydrates slurries during crystallization under laminar flowing |
topic_facet |
rheology cristallisation agglomeration laminar flowing [SPI.OTHER]Engineering Sciences [physics]/Other |
description |
10 pages An original experimental set-up was developed and used for studying crystallization and rheology of methane hydrate/water/dodecane system under laminar flowing. Dynamic viscosity and conversion of water and gas into gas hydrate crystals were measured during the process for various water contents. Experimental results were explained by means of a model including nucleation, growth and agglomeration. Due to the high value of crystal and drop concentrations, agglomeration takes place through three-bodies collisions between one water drop and two already formed agglomerates. Resulting agglomerates were considered as fractal-like ones. During crystallization and agglomeration, the effective volume fraction of drops and porous agglomerates is increased, then suspension viscosity increases. When all water drops are crystallized, agglomeration stops and viscosity do not change. |
author2 |
Centre Sciences des Processus Industriels et Naturels (SPIN-ENSMSE) École des Mines de Saint-Étienne (Mines Saint-Étienne MSE) Institut Mines-Télécom Paris (IMT)-Institut Mines-Télécom Paris (IMT) Département Géochimie, environnement, écoulement, réacteurs industriels et cristallisation (GENERIC-ENSMSE) Institut Mines-Télécom Paris (IMT)-Institut Mines-Télécom Paris (IMT)-SPIN Laboratoire des Procédés en Milieux Granulaires (LPMG-EMSE) Institut Mines-Télécom Paris (IMT)-Institut Mines-Télécom Paris (IMT)-Centre National de la Recherche Scientifique (CNRS) |
format |
Conference Object |
author |
FIDEL-DUFOUR, Annie Gruy, Frédéric Herri, Jean-Michel |
author_facet |
FIDEL-DUFOUR, Annie Gruy, Frédéric Herri, Jean-Michel |
author_sort |
FIDEL-DUFOUR, Annie |
title |
Rheological characterization and modelling of hydrates slurries during crystallization under laminar flowing |
title_short |
Rheological characterization and modelling of hydrates slurries during crystallization under laminar flowing |
title_full |
Rheological characterization and modelling of hydrates slurries during crystallization under laminar flowing |
title_fullStr |
Rheological characterization and modelling of hydrates slurries during crystallization under laminar flowing |
title_full_unstemmed |
Rheological characterization and modelling of hydrates slurries during crystallization under laminar flowing |
title_sort |
rheological characterization and modelling of hydrates slurries during crystallization under laminar flowing |
publisher |
HAL CCSD |
publishDate |
2005 |
url |
https://hal.archives-ouvertes.fr/hal-00125062 https://hal.archives-ouvertes.fr/hal-00125062/document https://hal.archives-ouvertes.fr/hal-00125062/file/ICHG5-AFD.pdf |
op_coverage |
Tromdheim, Norway |
geographic |
Norway |
geographic_facet |
Norway |
genre |
Methane hydrate |
genre_facet |
Methane hydrate |
op_source |
Fifth International Conference on Gas Hydrates (ICGH 5), Norvège, 13 au 16 juin 2005 https://hal.archives-ouvertes.fr/hal-00125062 Fifth International Conference on Gas Hydrates (ICGH 5), Norvège, 13 au 16 juin 2005, Jun 2005, Tromdheim, Norway |
op_relation |
hal-00125062 https://hal.archives-ouvertes.fr/hal-00125062 https://hal.archives-ouvertes.fr/hal-00125062/document https://hal.archives-ouvertes.fr/hal-00125062/file/ICHG5-AFD.pdf |
op_rights |
info:eu-repo/semantics/OpenAccess |
_version_ |
1766068708884611072 |