| Summary: | Downhole sampling of unboiled liquid at 1350 and 1500 m depth in the seawater-dominated Reykjanes high-temperature geothermal system in Iceland shows that metal concentrations measured at surface are minimum values due to mineral precipitation in the wells; by analogy of similar tectonic setting, host rocks and fluid composition, the metal concentrations measured in many black smoker vents at the seafloor are also minima. Fluids in the Reykjanes geothermal system react with mid-ocean ridge basalt at temperatures as high as 346°C and contain Fe 9-140 ppm, Cu 14-17 ppm, Zn 5-27 ppm, Pb 120-290 ppb, 1-6 ppb Au, and 28-107 ppb Ag. Fluids discharged at surface from the same wells have orders of magnitude lower metal concentrations due to precipitation caused by boiling and vapor loss during depressurization. Upstream of the orifice plate at high pressure (40 bar, 252°C) the precipitates consist mainly of sphalerite and chalcopyrite with a trace of galena and bornite. At the orifice plate of old wells, the pressure decreased sharply to 11 bar (188°C), resulting in abundant deposition of amorphous silica together with minor sphalerite and traces of chalcopyrite. In new wells the pressure at the orifice plate decreases to 22 bar (220°C); this pressure decrease and concomitant boiling causes deposition of fine-grained bornite-digenite solid solution together with sphalerite and galena on the fluid flow control valve. In high-pressure wells (average wellhead pressure 45-35 bar) most metals (mainly as sphalerite) are deposited downstream of the orifice plate, with up to 950 ppm Au and 2.5 wt.% Ag. Bulk concentrations in the scales vary between 15-60 wt.% upstream and downstream of the orifice plate and diminish from there. Iron increases up well from 8 to ~20 wt.% and decreases downstream of the orifice plate from 6 to 2 wt.% at the separation station; Cu downhole is ~3 wt.% but increases to 25 wt.% on the fluid flow control valve and then decreases; Pb downhole 100s ppm but at the wellhead is ~3 wt.%, increasing to 15 wt.% at the fluid flow control valve, then decreasing sharply from there.
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