| Summary: | Thesis advisor: Jeremy Shakun Thesis advisor: Tony Wang To better understand ice sheet and nutrient cycling dynamics in the North Atlantic, three geochemical paleo-proxies have been analyzed in Pleistocene marine sediments: cosmogenic nuclides (10Be and 26Al) in ice-rafted debris (IRD), 40Ar/39Ar in IRD, and foraminifera-bound nitrogen isotopes (FB-δ15N). For Chapter 1, we analyzed 10Be and 26Al concentrations in quartz separates of IRD from last-glacial North Atlantic sediments and used these data to constrain the history of Laurentide Ice Sheet (LIS) cover over Canada during the Pleistocene. While LIS history is well constrained since the Last Glacial Maximum (LGM) (~20,000 years ago), there is little evidence available from earlier times. 26Al/10Be ratios are depressed in these samples, the result of long-term decay under cover, which we suggest is best explained by a persistent LIS over much of the last million years. This finding implies that the LIS did not fully disappear during many Pleistocene interglacials, making the current ice-free Holocene interglacial relatively unique. For Chapter 2, we synthesized 3,762 40Ar/39Ar ages from North Atlantic IRD, including 670 new analyses. 595 of these single-grain analyses come from some of the same sample intervals as Chapter 1. These 40Ar/39Ar ages in IRD, a tracer of IRD provenance, clarify changes in North Atlantic ice sheet extent during the past few glacial cycles. Comparison of 40Ar/39Ar ages with hypothesized ice margins and cosmogenic nuclide data (from Chapter 1) aid in our interpretations. For last-glacial samples, results suggest ice sheets around the basin may have been in a retracted state during Marine Isotope Stage (MIS) 3 (~29-57 ka), an interval of debated ice extent for the LIS. Our synthesis also allows us to present the first complete records 40Ar/39Ar ages in IRD during Heinrich intervals – times when the LIS exhibited iceberg discharge events. These results support the suggestion made by previous work that Heinrich events 3 and 6 are ...
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