Vertical profiles of light absorption and scattering associated with black carbon particle fractions in the springtime Arctic above 79◦ N

• Published in: Atmospheric Chemistry and Physics
• Main Authors: Leaitch, W. Richard, Kodros, John K., Willis, Megan D., Hanna, Sarah J., Schulz, Hannes, Andrews, Elisabeth, Bozem, Heiko, Burkart, Julia, Hoor, Peter M., Kolonjari, Felicia, Orgren, J. A., Sharma, Sangeeta, Si, Meng, von Salzen, Knut, Bertram, Alan K, Herber, Andreas, Abbatt, Jonathan P.D., Pierce, Jeffrey R.
• Format: Article in Journal/Newspaper
• Language: unknown
• Published: COPERNICUS GESELLSCHAFT MBH 2020
• Subjects: albedo; Arctic; black carbon; Canadian Archipelago; Nunavut
• Online Access: https://epic.awi.de/id/eprint/52952/; https://epic.awi.de/id/eprint/52952/1/Leaitch-etal-ACP-2020.pdf; http://www.atmospheric-chemistry-and-physics.net; https://hdl.handle.net/10013/epic.6d4d8f4a-6a44-4db2-9954-9ce9847ae3fe

Despite the potential importance of black carbon (BC) for radiative forcing of the Arctic atmosphere, ver- tically resolved measurements of the particle light scatter- ing coefficient (σsp ) and light absorption coefficient (σap ) in the springtime Arctic atmosphere are infrequent, espe- cially measurements at latitudes at or above 80◦ N. Here, re- lationships among vertically distributed aerosol optical prop- erties (σap, σsp and single scattering albedo or SSA), par- ticle microphysics and particle chemistry are examined for a region of the Canadian archipelago between 79.9 and 83.4◦ N from near the surface to 500 hPa. Airborne data collected during April 2015 are combined with ground- based observations from the observatory at Alert, Nunavut and simulations from the Goddard Earth Observing Sys- tem (GEOS) model, GEOS-Chem, coupled with the TwO- Moment Aerosol Sectional (TOMAS) model (collectively GEOS-Chem–TOMAS; Kodros et al., 2018) to further our knowledge of the effects of BC on light absorption in the Arctic troposphere. The results are constrained for σsp less than 15 Mm−1, which represent 98 % of the observed σsp, be- cause the single scattering albedo (SSA) has a tendency to be lower at lower σsp, resulting in a larger relative contribution to Arctic warming. At 18.4 m2 g−1, the average BC mass ab- sorption coefficient (MAC) from the combined airborne and Alert observations is substantially higher than the two aver- aged modelled MAC values (13.6 and 9.1 m2 g−1) for two different internal mixing assumptions, the latter of which is based on previous observations. The higher observed MAC value may be explained by an underestimation of BC, the presence of small amounts of dust and/or possible differences in BC microphysics and morphologies between the obser- vations and model. In comparing the observations and simulations, we present σap and SSA, as measured, and σap/2 and the corresponding SSA to encompass the lower modelled MAC that is more consistent with accepted MAC values. Me- dian values of the ...