Deep ocean carbonate ion increase during mid Miocene CO2 decline

Characterised by long term cooling and abrupt ice sheet expansion on Antarctica ~14 Ma ago, the mid Miocene marked the beginning of the modern ice-house world, yet there is still little consensus on its causes, in part because carbon cycle dynamics are not well constrained. In particular, changes in...

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Bibliographic Details
Published in:Scientific Reports
Main Authors: Kender, S., Yu, Jimin, Peck, V.L.
Format: Article in Journal/Newspaper
Language:unknown
Published: Nature Publishing Group
Subjects:
Online Access:http://hdl.handle.net/1885/57446
https://doi.org/10.1038/srep04187
https://openresearch-repository.anu.edu.au/bitstream/1885/57446/5/Yu_2014_Deep_ocean.pdf.jpg
https://openresearch-repository.anu.edu.au/bitstream/1885/57446/7/01_Kender_Deep_ocean_carbonate_ion_2014.pdf.jpg
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Summary:Characterised by long term cooling and abrupt ice sheet expansion on Antarctica ~14 Ma ago, the mid Miocene marked the beginning of the modern ice-house world, yet there is still little consensus on its causes, in part because carbon cycle dynamics are not well constrained. In particular, changes in carbonate ion concentration ([CO3(2-)]) in the ocean, the largest carbon reservoir of the ocean-land-atmosphere system, are poorly resolved. We use benthic foraminiferal B/Ca ratios to reconstruct relative changes in [CO3(2-)] from the South Atlantic, East Pacific, and Southern Oceans. Our results suggest an increase of perhaps ~40 μmol/kg may have occurred between ~15 and 14 Ma in intermediate to deep waters in each basin. This long-term increase suggests elevated alkalinity input, perhaps from the Himalaya, rather than other shorter-term mechanisms such as ocean circulation or ecological changes, and may account for some of the proposed atmospheric CO2 decline before ~14 Ma.