Global temperature dependency of biogenic HCHO columns observed from space: Interpretation of TROPOMI results using GEOS-Chem model

Temperature is the principal driver of global HCHO and its primary oxidation precursor biogenic volatile organic compounds (BVOCs). We revisit such a temperature (T-) dependency globally, leveraging TROPOMI HCHO column data. We find substantial variations in the T-dependency of biogenic HCHO across...

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Bibliographic Details
Main Authors: Li, Xicheng, Zhu, Lei, Smedt, Isabelle De, Sun, Wenfu, Chen, Yuyang, Shu, Lei, Wang, Dakang, Liu, Song, Pu, Dongchuan, Li, Juan, Zuo, Xiaoxing, Fu, Weitao, Li, Yali, Zhang, Peng, Yan, Zhuoxian, Fu, Tzung-May, Shen, Huizhong, Wang, Chen, Ye, Jianhuai, Yang, Xin
Format: Other/Unknown Material
Language:unknown
Published: Authorea, Inc. 2024
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Online Access:http://dx.doi.org/10.22541/essoar.171805097.76930151/v1
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Summary:Temperature is the principal driver of global HCHO and its primary oxidation precursor biogenic volatile organic compounds (BVOCs). We revisit such a temperature (T-) dependency globally, leveraging TROPOMI HCHO column data. We find substantial variations in the T-dependency of biogenic HCHO across plant functional types (PFTs), with the highest over Broadleaf Evergreen Tropical Trees (doubling every 6.0 K ± 2.1 K) and lowest over Arctic C3 Grass (doubling every 30.8 K ± 9.6 K). The GEOS-Chem model interprets HCHO columns’ T-dependency at the PFT level (r = 0.87), with a 16% discrepancy on average. The discrepancy can be explained by BVOC emissions T-dependency for Broadleaf Evergreen Tropical Trees and Warm C4 Grass and can be attributed to the insensitivity of HCHO columns to BVOC emissions for other PFTs. Our findings underscore a potentially magnified variation of BVOC emissions by GEOS-Chem and MEGAN therein, particularly in regions experiencing greater temperature variations.