The sources of alkalinity in Lake Miklavatn, north Iceland

Lake Miklavatn, north Iceland, is highly stratified with an 8–9‐m layer of freshwater overlying saline and anoxic deeper water. Sulfide and ammonia concentrations are high in the stagnant and saline layer, and titration alkalinity exceeds conservative alkalinity in the deepest part of the lake by a...

Full description

Bibliographic Details
Published in:Limnology and Oceanography
Main Authors: Einarsson, Stefan, Stefánsson, Unnsteinn
Format: Article in Journal/Newspaper
Language:English
Published: Wiley 1983
Subjects:
Online Access:http://dx.doi.org/10.4319/lo.1983.28.1.0050
https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.4319%2Flo.1983.28.1.0050
https://aslopubs.onlinelibrary.wiley.com/doi/pdf/10.4319/lo.1983.28.1.0050
Description
Summary:Lake Miklavatn, north Iceland, is highly stratified with an 8–9‐m layer of freshwater overlying saline and anoxic deeper water. Sulfide and ammonia concentrations are high in the stagnant and saline layer, and titration alkalinity exceeds conservative alkalinity in the deepest part of the lake by a factor of 3–4. Reduction of sulfate was estimated by direct measurement of the sulfate concentration. With one exception the decrease in sulfate was found to exceed the measured sulfide concentration. This is explained by partial oxidation of sulfide due to mixing with oxygenated water from the upper layer. The excess alkalinity is 92–93% accounted for by sulfate reduction and formation of ammonia, whereas excess metal carbonates do not seem to be a source.