Ambient and cold‐temperature infrared spectra and XRD patterns of ammoniated phyllosilicates and carbonaceous chondrite meteorites relevant to Ceres and other solar system bodies

• Published in: Meteoritics & Planetary Science
• Main Authors: Ehlmann, Bethany L., Hodyss, Robert, Bristow, Thomas F., Rossman, George R., Ammannito, Eleonora, De Sanctis, M. Cristina, Raymond, Carol A.
• Other Authors: National Aeronautics and Space Administration
• Format: Article in Journal/Newspaper
• Language: English
• Published: Wiley 2018
• Subjects: Tagish; Tagish Lake
• Online Access: http://dx.doi.org/10.1111/maps.13103; https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1111%2Fmaps.13103; https://onlinelibrary.wiley.com/doi/pdf/10.1111/maps.13103; https://onlinelibrary.wiley.com/doi/full-xml/10.1111/maps.13103

Abstract Mg‐phyllosilicate‐bearing, dark surface materials on the dwarf planet Ceres have NH 4 ‐bearing materials, indicated by a distinctive 3.06 μm absorption feature. To constrain the identity of the Ceres NH 4 ‐carrier phase(s), we ammoniated ground particulates of candidate materials to compare their spectral properties to infrared data acquired by Dawn's Visible and Infrared (VIR) imaging spectrometer. We treated Mg‐, Fe‐, and Al‐smectite clay minerals; Mg‐serpentines; Mg‐chlorite; and a suite of carbonaceous meteorites with NH 4 ‐acetate to exchange ammonium. Serpentines and chlorites showed no evidence for ammoniation, as expected due to their lack of exchangeable interlayer sites. Most smectites showed evidence for ammoniation by incorporation of NH 4 + into their interlayers, resulting in the appearance of absorptions from 3.02 to 3.08 μm. Meteorite samples tested had weak absorptions between 3.0 and 3.1 μm but showed little clear evidence for enhancement upon ammoniation, likely due to the high proportion of serpentine and other minerals relative to expandable smectite phases or to NH 4 + complexing with organics or other constituents. The wavelength position of the smectite NH 4 absorption showed no variation between IR spectra acquired under dry‐air purge at 25 °C and under vacuum at 25 °C to −180 °C. Collectively, data from the smectite samples show that the precise center wavelength of the characteristic ~3.05 μm v 3 absorption in NH 4 is variable and is likely related to the degree of hydrogen bonding of NH 4 ‐H 2 O complexes. Comparison with Dawn VIR spectra indicates that the hypothesis of Mg‐saponite as the ammonium carrier phase is the simplest explanation for observed data, and that Ceres dark materials may be like Cold Bokkeveld or Tagish Lake but with proportionally more Mg‐smectite.