Associations of organic matter with minerals in Tagish Lake meteorite via high spatial resolution synchrotron‐based FTIR microspectroscopy

• Published in: Meteoritics & Planetary Science
• Main Authors: Yesiltas, Mehmet, Kebukawa, Yoko
• Other Authors: University of Wisconsin-Madison, University of Wisconsin-Milwaukee, National Science Foundation
• Format: Article in Journal/Newspaper
• Language: English
• Published: Wiley 2016
• Subjects: Tagish; Tagish Lake
• Online Access: http://dx.doi.org/10.1111/maps.12609; https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1111%2Fmaps.12609; https://onlinelibrary.wiley.com/doi/pdf/10.1111/maps.12609; https://onlinelibrary.wiley.com/doi/full-xml/10.1111/maps.12609; https://onlinelibrary.wiley.com/doi/am-pdf/10.1111/maps.12609

Abstract We have investigated spatial and spectral associations between mineral species and organic matter in the Tagish Lake meteorite. Synchrotron‐based infrared microspectroscopy allowed us to spatially locate specific organic and inorganic compounds within multiple Tagish Lake grains with high spatial resolution. Generated two‐dimensional infrared maps present strong spatial association between aliphatic C‐H and OH in phyllosilicates in Tagish Lake grains. These observations indicate possible roles of phyllosilicates for the formation, evolution, and preservation of organic matter. Infared spectra of all studied Tagish Lake grains show a strong carbonate band, which also shows a weak but positive correlation with organic matter in some grains. However, intergrain correlation was not observed between carbonates and organics, which is likely due to the difference of carbonate occurrence, e.g., presence of larger grains or intergrowth of carbonates on phyllosilicates. Possible scenarios further explaining the observed associations of organics with phyllosilicates and carbonates are presented.