Melted micrometeorites from Antarctic ice with evidence for the separation of immiscible Fe‐Ni‐S liquids during entry heating

• Published in: Meteoritics & Planetary Science
• Main Authors: GENGE, MATTHEW J., GRADY, MONICA M.
• Format: Article in Journal/Newspaper
• Language: English
• Published: Wiley 1998
• Subjects: Antarctic; Antarc*
• Online Access: http://dx.doi.org/10.1111/j.1945-5100.1998.tb01647.x; https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1111%2Fj.1945-5100.1998.tb01647.x; https://onlinelibrary.wiley.com/doi/pdf/10.1111/j.1945-5100.1998.tb01647.x

Abstract— We report the discovery of four large (>50 μm) cosmic spherules (CSs) and a single scoriaceous micrometeorite (SMM) that contain evidence for the separation of immiscible Fe‐Ni‐S liquids during atmospheric entry heating. The particles contain segregated Fe‐rich regions dominated by either Ni‐S‐bearing Fe‐oxides or iron sulphides and have textural relations that suggest these separated from the silicate portions of the particles as metallic liquids. The oxides, which may be hydrous, are thought to result from alteration of metal and sulphide. The compositions of the silicate portions of the CSs are equivalent to spherules without Fe‐rich regions, implying that metallic liquids are exsolved during the heating of most spherules, but completely separate. The single SMM has a very different composition from other scoriaceous particles, and the occurrence of an exsolved metallic liquid probably indicates extreme reduction during entry heating. The pyrolysis of carbonaceous materials is the most likely explanation for reduction and suggests that the precursor material of this particle was unusually C‐rich. This SMM might be, therefore, an appropriate candidate for a large melted anhydrous or smectite interplanetary dust particle (IDP). The exsolution of immiscible Fe‐Ni‐S liquids during entry heating will result in systematic changes in the compositions of the remaining silicate melt.