Lipase Catalysis in Ionic Liquids and Supercritical Carbon Dioxide at 150 °C

Abstract Free and immobilized Candida antarctica lipase B dispersed in ionic liquids (1‐ethyl‐3‐methylimidazolium bistriflimide and 1‐buthyl‐3‐methylimidazolium bistriflimide) were used as catalyst for the continuous kinetic resolution of rac ‐1‐phenylethanol in supercritical carbon dioxide at 120 a...

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Bibliographic Details
Published in:Biotechnology Progress
Main Authors: Lozano, Pedro, de Diego, Teresa, Carrié, Daniel, Vaultier, Michel, Iborra, José L.
Format: Article in Journal/Newspaper
Language:English
Published: Wiley 2003
Subjects:
Antarc*
Antarctica
Online Access:http://dx.doi.org/10.1021/bp025759o
https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1021%2Fbp025759o
https://onlinelibrary.wiley.com/doi/full/10.1021/bp025759o
Description
Summary:Abstract Free and immobilized Candida antarctica lipase B dispersed in ionic liquids (1‐ethyl‐3‐methylimidazolium bistriflimide and 1‐buthyl‐3‐methylimidazolium bistriflimide) were used as catalyst for the continuous kinetic resolution of rac ‐1‐phenylethanol in supercritical carbon dioxide at 120 and 150 °C and 10 MPa. Excellent activity, stability and enantioselectivity levels were recorded in continuous operation.

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