Hydrogen isotope analysis of natural abundance and deuterium‐enriched waters by reduction over chromium on‐line to a dynamic dual inlet isotope‐ratio mass spectrometer
Abstract This paper describes the application of a simple chromium reduction furnace which can be interfaced with a dual inlet isotope‐ratio mass spectrometer thus providing the capacity for cheap, fast, accurate and precise measurement of δD V−SMOW by dynamic mass spectrometry. Measurements are pre...
Published in: | Rapid Communications in Mass Spectrometry |
---|---|
Main Authors: | , , , , |
Format: | Article in Journal/Newspaper |
Language: | English |
Published: |
Wiley
2001
|
Subjects: | |
Online Access: | http://dx.doi.org/10.1002/rcm.361 https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Frcm.361 https://onlinelibrary.wiley.com/doi/full/10.1002/rcm.361 |
id |
crwiley:10.1002/rcm.361 |
---|---|
record_format |
openpolar |
spelling |
crwiley:10.1002/rcm.361 2024-09-15T17:41:04+00:00 Hydrogen isotope analysis of natural abundance and deuterium‐enriched waters by reduction over chromium on‐line to a dynamic dual inlet isotope‐ratio mass spectrometer Donnelly, Terry Waldron, Susan Tait, Andrew Dougans, Julie Bearhop, Stuart 2001 http://dx.doi.org/10.1002/rcm.361 https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Frcm.361 https://onlinelibrary.wiley.com/doi/full/10.1002/rcm.361 en eng Wiley http://onlinelibrary.wiley.com/termsAndConditions#vor Rapid Communications in Mass Spectrometry volume 15, issue 15, page 1297-1303 ISSN 0951-4198 1097-0231 journal-article 2001 crwiley https://doi.org/10.1002/rcm.361 2024-08-06T04:21:18Z Abstract This paper describes the application of a simple chromium reduction furnace which can be interfaced with a dual inlet isotope‐ratio mass spectrometer thus providing the capacity for cheap, fast, accurate and precise measurement of δD V−SMOW by dynamic mass spectrometry. Measurements are precise to the order of ≤0.5‰. Mean 95% confidence intervals for the Vienna Standard Mean Ocean Water (V‐SMOW) to Standard Light Antarctic Precipitation (SLAP) range are in the order of 2.5‰ and the system is linear over the range −428 to 23,000‰. Memory effects do exist, but are small for natural abundance samples and can be minimised by careful planning of the analytical load. Copyright © 2001 John Wiley & Sons, Ltd. Article in Journal/Newspaper Antarc* Antarctic Wiley Online Library Rapid Communications in Mass Spectrometry 15 15 1297 1303 |
institution |
Open Polar |
collection |
Wiley Online Library |
op_collection_id |
crwiley |
language |
English |
description |
Abstract This paper describes the application of a simple chromium reduction furnace which can be interfaced with a dual inlet isotope‐ratio mass spectrometer thus providing the capacity for cheap, fast, accurate and precise measurement of δD V−SMOW by dynamic mass spectrometry. Measurements are precise to the order of ≤0.5‰. Mean 95% confidence intervals for the Vienna Standard Mean Ocean Water (V‐SMOW) to Standard Light Antarctic Precipitation (SLAP) range are in the order of 2.5‰ and the system is linear over the range −428 to 23,000‰. Memory effects do exist, but are small for natural abundance samples and can be minimised by careful planning of the analytical load. Copyright © 2001 John Wiley & Sons, Ltd. |
format |
Article in Journal/Newspaper |
author |
Donnelly, Terry Waldron, Susan Tait, Andrew Dougans, Julie Bearhop, Stuart |
spellingShingle |
Donnelly, Terry Waldron, Susan Tait, Andrew Dougans, Julie Bearhop, Stuart Hydrogen isotope analysis of natural abundance and deuterium‐enriched waters by reduction over chromium on‐line to a dynamic dual inlet isotope‐ratio mass spectrometer |
author_facet |
Donnelly, Terry Waldron, Susan Tait, Andrew Dougans, Julie Bearhop, Stuart |
author_sort |
Donnelly, Terry |
title |
Hydrogen isotope analysis of natural abundance and deuterium‐enriched waters by reduction over chromium on‐line to a dynamic dual inlet isotope‐ratio mass spectrometer |
title_short |
Hydrogen isotope analysis of natural abundance and deuterium‐enriched waters by reduction over chromium on‐line to a dynamic dual inlet isotope‐ratio mass spectrometer |
title_full |
Hydrogen isotope analysis of natural abundance and deuterium‐enriched waters by reduction over chromium on‐line to a dynamic dual inlet isotope‐ratio mass spectrometer |
title_fullStr |
Hydrogen isotope analysis of natural abundance and deuterium‐enriched waters by reduction over chromium on‐line to a dynamic dual inlet isotope‐ratio mass spectrometer |
title_full_unstemmed |
Hydrogen isotope analysis of natural abundance and deuterium‐enriched waters by reduction over chromium on‐line to a dynamic dual inlet isotope‐ratio mass spectrometer |
title_sort |
hydrogen isotope analysis of natural abundance and deuterium‐enriched waters by reduction over chromium on‐line to a dynamic dual inlet isotope‐ratio mass spectrometer |
publisher |
Wiley |
publishDate |
2001 |
url |
http://dx.doi.org/10.1002/rcm.361 https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Frcm.361 https://onlinelibrary.wiley.com/doi/full/10.1002/rcm.361 |
genre |
Antarc* Antarctic |
genre_facet |
Antarc* Antarctic |
op_source |
Rapid Communications in Mass Spectrometry volume 15, issue 15, page 1297-1303 ISSN 0951-4198 1097-0231 |
op_rights |
http://onlinelibrary.wiley.com/termsAndConditions#vor |
op_doi |
https://doi.org/10.1002/rcm.361 |
container_title |
Rapid Communications in Mass Spectrometry |
container_volume |
15 |
container_issue |
15 |
container_start_page |
1297 |
op_container_end_page |
1303 |
_version_ |
1810487141295194112 |