Hydrogen isotope analysis of natural abundance and deuterium‐enriched waters by reduction over chromium on‐line to a dynamic dual inlet isotope‐ratio mass spectrometer

Abstract This paper describes the application of a simple chromium reduction furnace which can be interfaced with a dual inlet isotope‐ratio mass spectrometer thus providing the capacity for cheap, fast, accurate and precise measurement of δD V−SMOW by dynamic mass spectrometry. Measurements are pre...

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Bibliographic Details
Published in:Rapid Communications in Mass Spectrometry
Main Authors: Donnelly, Terry, Waldron, Susan, Tait, Andrew, Dougans, Julie, Bearhop, Stuart
Format: Article in Journal/Newspaper
Language:English
Published: Wiley 2001
Subjects:
Antarctic
Antarc*
Online Access:http://dx.doi.org/10.1002/rcm.361
https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Frcm.361
https://onlinelibrary.wiley.com/doi/full/10.1002/rcm.361
Description
Summary:Abstract This paper describes the application of a simple chromium reduction furnace which can be interfaced with a dual inlet isotope‐ratio mass spectrometer thus providing the capacity for cheap, fast, accurate and precise measurement of δD V−SMOW by dynamic mass spectrometry. Measurements are precise to the order of ≤0.5‰. Mean 95% confidence intervals for the Vienna Standard Mean Ocean Water (V‐SMOW) to Standard Light Antarctic Precipitation (SLAP) range are in the order of 2.5‰ and the system is linear over the range −428 to 23,000‰. Memory effects do exist, but are small for natural abundance samples and can be minimised by careful planning of the analytical load. Copyright © 2001 John Wiley & Sons, Ltd.

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