Simple and economical CALB/polyethylene/aluminum biocatalyst for fatty acid esterification
Candida antarctica lipase B was immobilized for the first time (at the author's knowledge) onto linear low density polyethylene (LLDPE) films. Polymer films were previously bonded to a commercial aluminum sheet using a simple support preparation method. Biocatalyst performance was evaluated in...
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crwiley:10.1002/pat.4189 2024-06-02T07:57:16+00:00 Simple and economical CALB/polyethylene/aluminum biocatalyst for fatty acid esterification Cavallaro, Valeria Ercoli, Daniel Ricardo Tonetto, Gabriela Marta Ferreira, María Luján National Council for Scientific and Technological Research, CONICET, Argentina National Agency of Scientific and Technological Promotion, Argentina 2017 http://dx.doi.org/10.1002/pat.4189 https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fpat.4189 https://onlinelibrary.wiley.com/doi/pdf/10.1002/pat.4189 en eng Wiley http://onlinelibrary.wiley.com/termsAndConditions#vor Polymers for Advanced Technologies volume 29, issue 2, page 1002-1006 ISSN 1042-7147 1099-1581 journal-article 2017 crwiley https://doi.org/10.1002/pat.4189 2024-05-03T10:50:42Z Candida antarctica lipase B was immobilized for the first time (at the author's knowledge) onto linear low density polyethylene (LLDPE) films. Polymer films were previously bonded to a commercial aluminum sheet using a simple support preparation method. Biocatalyst performance was evaluated in penthyl oleate synthesis at room temperature. Two different catalyst geometries were tested and compared: one aluminum‐polyethylene 50 mm × 50 mm foil (50CAT) or near 5 mm × 5 mm aluminum‐polyethylene foils (5CAT). The obtained results demonstrate that the biocatalyst obtained with 50 mm × 50 mm aluminum‐polyethylene foil or 50CAT is reusable in up to 7 cycles, easy to separate from reaction products, and economical in comparison with commercial Novozym 435. Novel and economical CALB/LLDPE/Al biocatalyst is an attractive alternative for possible applications in a continuous monolithic reactor and future industrial scaling up. Article in Journal/Newspaper Antarc* Antarctica Wiley Online Library Polymers for Advanced Technologies 29 2 1002 1006 |
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Open Polar |
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Wiley Online Library |
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crwiley |
language |
English |
description |
Candida antarctica lipase B was immobilized for the first time (at the author's knowledge) onto linear low density polyethylene (LLDPE) films. Polymer films were previously bonded to a commercial aluminum sheet using a simple support preparation method. Biocatalyst performance was evaluated in penthyl oleate synthesis at room temperature. Two different catalyst geometries were tested and compared: one aluminum‐polyethylene 50 mm × 50 mm foil (50CAT) or near 5 mm × 5 mm aluminum‐polyethylene foils (5CAT). The obtained results demonstrate that the biocatalyst obtained with 50 mm × 50 mm aluminum‐polyethylene foil or 50CAT is reusable in up to 7 cycles, easy to separate from reaction products, and economical in comparison with commercial Novozym 435. Novel and economical CALB/LLDPE/Al biocatalyst is an attractive alternative for possible applications in a continuous monolithic reactor and future industrial scaling up. |
author2 |
National Council for Scientific and Technological Research, CONICET, Argentina National Agency of Scientific and Technological Promotion, Argentina |
format |
Article in Journal/Newspaper |
author |
Cavallaro, Valeria Ercoli, Daniel Ricardo Tonetto, Gabriela Marta Ferreira, María Luján |
spellingShingle |
Cavallaro, Valeria Ercoli, Daniel Ricardo Tonetto, Gabriela Marta Ferreira, María Luján Simple and economical CALB/polyethylene/aluminum biocatalyst for fatty acid esterification |
author_facet |
Cavallaro, Valeria Ercoli, Daniel Ricardo Tonetto, Gabriela Marta Ferreira, María Luján |
author_sort |
Cavallaro, Valeria |
title |
Simple and economical CALB/polyethylene/aluminum biocatalyst for fatty acid esterification |
title_short |
Simple and economical CALB/polyethylene/aluminum biocatalyst for fatty acid esterification |
title_full |
Simple and economical CALB/polyethylene/aluminum biocatalyst for fatty acid esterification |
title_fullStr |
Simple and economical CALB/polyethylene/aluminum biocatalyst for fatty acid esterification |
title_full_unstemmed |
Simple and economical CALB/polyethylene/aluminum biocatalyst for fatty acid esterification |
title_sort |
simple and economical calb/polyethylene/aluminum biocatalyst for fatty acid esterification |
publisher |
Wiley |
publishDate |
2017 |
url |
http://dx.doi.org/10.1002/pat.4189 https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fpat.4189 https://onlinelibrary.wiley.com/doi/pdf/10.1002/pat.4189 |
genre |
Antarc* Antarctica |
genre_facet |
Antarc* Antarctica |
op_source |
Polymers for Advanced Technologies volume 29, issue 2, page 1002-1006 ISSN 1042-7147 1099-1581 |
op_rights |
http://onlinelibrary.wiley.com/termsAndConditions#vor |
op_doi |
https://doi.org/10.1002/pat.4189 |
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Polymers for Advanced Technologies |
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29 |
container_issue |
2 |
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1002 |
op_container_end_page |
1006 |
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1800740421561745408 |