Simple and economical CALB/polyethylene/aluminum biocatalyst for fatty acid esterification
Candida antarctica lipase B was immobilized for the first time (at the author's knowledge) onto linear low density polyethylene (LLDPE) films. Polymer films were previously bonded to a commercial aluminum sheet using a simple support preparation method. Biocatalyst performance was evaluated in...
| Published in: | Polymers for Advanced Technologies |
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| Main Authors: | , , , |
| Other Authors: | , |
| Format: | Article in Journal/Newspaper |
| Language: | English |
| Published: |
Wiley
2017
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| Subjects: | |
| Online Access: | http://dx.doi.org/10.1002/pat.4189 https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fpat.4189 https://onlinelibrary.wiley.com/doi/pdf/10.1002/pat.4189 |
| Summary: | Candida antarctica lipase B was immobilized for the first time (at the author's knowledge) onto linear low density polyethylene (LLDPE) films. Polymer films were previously bonded to a commercial aluminum sheet using a simple support preparation method. Biocatalyst performance was evaluated in penthyl oleate synthesis at room temperature. Two different catalyst geometries were tested and compared: one aluminum‐polyethylene 50 mm × 50 mm foil (50CAT) or near 5 mm × 5 mm aluminum‐polyethylene foils (5CAT). The obtained results demonstrate that the biocatalyst obtained with 50 mm × 50 mm aluminum‐polyethylene foil or 50CAT is reusable in up to 7 cycles, easy to separate from reaction products, and economical in comparison with commercial Novozym 435. Novel and economical CALB/LLDPE/Al biocatalyst is an attractive alternative for possible applications in a continuous monolithic reactor and future industrial scaling up. |
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