Enzymes in polymer chemistry, 8 Chemoenzymatic synthesis of polymerizable 11‐methacryloyl‐aminoundecanoic ester of 1‐ and 3‐ O‐methyl‐α‐ D‐glucose in 6‐ O‐position

Abstract The paper describes the regioselective esterification of a glucopyranoside and glucose derivative with 11‐methacryloylaminoundecanoic acid in the presence of a lipase from Candida antarctica . The obtained modified sugar derivatives 6‐ O ‐(11‐methacryloylaminoundecanoyl)‐1‐ O ‐methyl‐α‐ D ‐...

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Bibliographic Details
Published in:Macromolecular Rapid Communications
Main Authors: Geyer, Ulrike, Klemm, Dieter, Pavel, Konstantin, Ritter, Helmut
Format: Article in Journal/Newspaper
Language:English
Published: Wiley 1995
Subjects:
Antarc*
Antarctica
Online Access:http://dx.doi.org/10.1002/marc.1995.030160417
https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fmarc.1995.030160417
https://onlinelibrary.wiley.com/doi/pdf/10.1002/marc.1995.030160417
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Summary:Abstract The paper describes the regioselective esterification of a glucopyranoside and glucose derivative with 11‐methacryloylaminoundecanoic acid in the presence of a lipase from Candida antarctica . The obtained modified sugar derivatives 6‐ O ‐(11‐methacryloylaminoundecanoyl)‐1‐ O ‐methyl‐α‐ D ‐glucopyranoside (3 a) and 6‐ O ‐(11‐methacryloylaminoundecanoyl)‐3‐ O ‐methyl‐α‐ D ‐glucopyranose (3 b) were polymerized radically with AIBN as initiator.

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