Catalytic Synthesis of Functional Silicon‐Stereogenic Silanes through Candida antarctica Lipase B Catalyzed Remote Desymmetrization of Silicon‐Centered Diols

Abstract A series of silicon‐containing diols are synthesized and used in lipase‐catalyzed remote desymmetrization. This synthetic method is valuable in the construction of optically active silicon‐stereogenic organosilicon compounds. Good enantioselectivities of the remote desymmetrization was achi...

Full description

Bibliographic Details
Published in:European Journal of Organic Chemistry
Main Authors: Lu, Xing, Li, Li, Yang, Wei, Jiang, Kezhi, Yang, Ke‐Fang, Zheng, Zhan‐Jiang, Xu, Li‐Wen
Format: Article in Journal/Newspaper
Language:English
Published: Wiley 2013
Subjects:
Antarc*
Antarctica
Online Access:http://dx.doi.org/10.1002/ejoc.201300932
https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fejoc.201300932
http://onlinelibrary.wiley.com/wol1/doi/10.1002/ejoc.201300932/fullpdf
id crwiley:10.1002/ejoc.201300932
record_format openpolar
spelling crwiley:10.1002/ejoc.201300932 2024-09-15T17:41:20+00:00 Catalytic Synthesis of Functional Silicon‐Stereogenic Silanes through Candida antarctica Lipase B Catalyzed Remote Desymmetrization of Silicon‐Centered Diols Lu, Xing Li, Li Yang, Wei Jiang, Kezhi Yang, Ke‐Fang Zheng, Zhan‐Jiang Xu, Li‐Wen 2013 http://dx.doi.org/10.1002/ejoc.201300932 https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fejoc.201300932 http://onlinelibrary.wiley.com/wol1/doi/10.1002/ejoc.201300932/fullpdf en eng Wiley http://onlinelibrary.wiley.com/termsAndConditions#vor European Journal of Organic Chemistry volume 2013, issue 26, page 5814-5819 ISSN 1434-193X 1099-0690 journal-article 2013 crwiley https://doi.org/10.1002/ejoc.201300932 2024-08-30T04:12:21Z Abstract A series of silicon‐containing diols are synthesized and used in lipase‐catalyzed remote desymmetrization. This synthetic method is valuable in the construction of optically active silicon‐stereogenic organosilicon compounds. Good enantioselectivities of the remote desymmetrization was achieved with Candida antarctica lipase B (CAL‐B) (up to 90:10 er ). Article in Journal/Newspaper Antarc* Antarctica Wiley Online Library European Journal of Organic Chemistry 2013 26 5814 5819
institution Open Polar
collection Wiley Online Library
op_collection_id crwiley
language English
description Abstract A series of silicon‐containing diols are synthesized and used in lipase‐catalyzed remote desymmetrization. This synthetic method is valuable in the construction of optically active silicon‐stereogenic organosilicon compounds. Good enantioselectivities of the remote desymmetrization was achieved with Candida antarctica lipase B (CAL‐B) (up to 90:10 er ).
format Article in Journal/Newspaper
author Lu, Xing
Li, Li
Yang, Wei
Jiang, Kezhi
Yang, Ke‐Fang
Zheng, Zhan‐Jiang
Xu, Li‐Wen
spellingShingle Lu, Xing
Li, Li
Yang, Wei
Jiang, Kezhi
Yang, Ke‐Fang
Zheng, Zhan‐Jiang
Xu, Li‐Wen
Catalytic Synthesis of Functional Silicon‐Stereogenic Silanes through Candida antarctica Lipase B Catalyzed Remote Desymmetrization of Silicon‐Centered Diols
author_facet Lu, Xing
Li, Li
Yang, Wei
Jiang, Kezhi
Yang, Ke‐Fang
Zheng, Zhan‐Jiang
Xu, Li‐Wen
author_sort Lu, Xing
title Catalytic Synthesis of Functional Silicon‐Stereogenic Silanes through Candida antarctica Lipase B Catalyzed Remote Desymmetrization of Silicon‐Centered Diols
title_short Catalytic Synthesis of Functional Silicon‐Stereogenic Silanes through Candida antarctica Lipase B Catalyzed Remote Desymmetrization of Silicon‐Centered Diols
title_full Catalytic Synthesis of Functional Silicon‐Stereogenic Silanes through Candida antarctica Lipase B Catalyzed Remote Desymmetrization of Silicon‐Centered Diols
title_fullStr Catalytic Synthesis of Functional Silicon‐Stereogenic Silanes through Candida antarctica Lipase B Catalyzed Remote Desymmetrization of Silicon‐Centered Diols
title_full_unstemmed Catalytic Synthesis of Functional Silicon‐Stereogenic Silanes through Candida antarctica Lipase B Catalyzed Remote Desymmetrization of Silicon‐Centered Diols
title_sort catalytic synthesis of functional silicon‐stereogenic silanes through candida antarctica lipase b catalyzed remote desymmetrization of silicon‐centered diols
publisher Wiley
publishDate 2013
url http://dx.doi.org/10.1002/ejoc.201300932
https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fejoc.201300932
http://onlinelibrary.wiley.com/wol1/doi/10.1002/ejoc.201300932/fullpdf
genre Antarc*
Antarctica
genre_facet Antarc*
Antarctica
op_source European Journal of Organic Chemistry
volume 2013, issue 26, page 5814-5819
ISSN 1434-193X 1099-0690
op_rights http://onlinelibrary.wiley.com/termsAndConditions#vor
op_doi https://doi.org/10.1002/ejoc.201300932
container_title European Journal of Organic Chemistry
container_volume 2013
container_issue 26
container_start_page 5814
op_container_end_page 5819
_version_ 1810487493560107008

Similar Items