Metal‐Free Directed ortho C–H Iodination: Synthesis of 2′‐Iodobiaryl‐2‐carbonitriles

Abstract Metal‐free directed ortho C–H iodination of biaryl‐2‐carbonitriles was developed. A series of 2′‐iodobiaryl‐2‐carbonitriles were synthesized from substituted biphenylcarbonitriles and naphthylbenzonitriles in reasonably good yields by using bis(pyridine)iodonium(I) tetrafluoroborate (IPy 2...

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Published in:European Journal of Organic Chemistry
Main Authors: Sarkar, Satinath, Jana, Manoranjan, Narender, Tadigoppula
Format: Article in Journal/Newspaper
Language:English
Published: Wiley 2013
Subjects:
IPY
Online Access:http://dx.doi.org/10.1002/ejoc.201300584
https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fejoc.201300584
https://onlinelibrary.wiley.com/doi/full/10.1002/ejoc.201300584
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spelling crwiley:10.1002/ejoc.201300584 2024-06-02T08:09:35+00:00 Metal‐Free Directed ortho C–H Iodination: Synthesis of 2′‐Iodobiaryl‐2‐carbonitriles Sarkar, Satinath Jana, Manoranjan Narender, Tadigoppula 2013 http://dx.doi.org/10.1002/ejoc.201300584 https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fejoc.201300584 https://onlinelibrary.wiley.com/doi/full/10.1002/ejoc.201300584 en eng Wiley http://onlinelibrary.wiley.com/termsAndConditions#vor European Journal of Organic Chemistry volume 2013, issue 29, page 6491-6495 ISSN 1434-193X 1099-0690 journal-article 2013 crwiley https://doi.org/10.1002/ejoc.201300584 2024-05-03T11:40:50Z Abstract Metal‐free directed ortho C–H iodination of biaryl‐2‐carbonitriles was developed. A series of 2′‐iodobiaryl‐2‐carbonitriles were synthesized from substituted biphenylcarbonitriles and naphthylbenzonitriles in reasonably good yields by using bis(pyridine)iodonium(I) tetrafluoroborate (IPy 2 BF 4 , Barluenga's reagent) and HBF 4 · OEt 2 . The biaryl‐2‐carbonitriles are useful precursors for the synthesis of benzocyclic ketones. Article in Journal/Newspaper IPY Wiley Online Library European Journal of Organic Chemistry 2013 29 6491 6495
institution Open Polar
collection Wiley Online Library
op_collection_id crwiley
language English
description Abstract Metal‐free directed ortho C–H iodination of biaryl‐2‐carbonitriles was developed. A series of 2′‐iodobiaryl‐2‐carbonitriles were synthesized from substituted biphenylcarbonitriles and naphthylbenzonitriles in reasonably good yields by using bis(pyridine)iodonium(I) tetrafluoroborate (IPy 2 BF 4 , Barluenga's reagent) and HBF 4 · OEt 2 . The biaryl‐2‐carbonitriles are useful precursors for the synthesis of benzocyclic ketones.
format Article in Journal/Newspaper
author Sarkar, Satinath
Jana, Manoranjan
Narender, Tadigoppula
spellingShingle Sarkar, Satinath
Jana, Manoranjan
Narender, Tadigoppula
Metal‐Free Directed ortho C–H Iodination: Synthesis of 2′‐Iodobiaryl‐2‐carbonitriles
author_facet Sarkar, Satinath
Jana, Manoranjan
Narender, Tadigoppula
author_sort Sarkar, Satinath
title Metal‐Free Directed ortho C–H Iodination: Synthesis of 2′‐Iodobiaryl‐2‐carbonitriles
title_short Metal‐Free Directed ortho C–H Iodination: Synthesis of 2′‐Iodobiaryl‐2‐carbonitriles
title_full Metal‐Free Directed ortho C–H Iodination: Synthesis of 2′‐Iodobiaryl‐2‐carbonitriles
title_fullStr Metal‐Free Directed ortho C–H Iodination: Synthesis of 2′‐Iodobiaryl‐2‐carbonitriles
title_full_unstemmed Metal‐Free Directed ortho C–H Iodination: Synthesis of 2′‐Iodobiaryl‐2‐carbonitriles
title_sort metal‐free directed ortho c–h iodination: synthesis of 2′‐iodobiaryl‐2‐carbonitriles
publisher Wiley
publishDate 2013
url http://dx.doi.org/10.1002/ejoc.201300584
https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fejoc.201300584
https://onlinelibrary.wiley.com/doi/full/10.1002/ejoc.201300584
genre IPY
genre_facet IPY
op_source European Journal of Organic Chemistry
volume 2013, issue 29, page 6491-6495
ISSN 1434-193X 1099-0690
op_rights http://onlinelibrary.wiley.com/termsAndConditions#vor
op_doi https://doi.org/10.1002/ejoc.201300584
container_title European Journal of Organic Chemistry
container_volume 2013
container_issue 29
container_start_page 6491
op_container_end_page 6495
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