ChemInform Abstract: Metalated Nitrogen Derivatives of Carbonic Acid in Organic Synthesis. Part 31. α‐Deprotonation of an α‐Chiral 2‐Alkenylcarbamate with Retention and Lithium‐Titanium Exchange with Inversion ‐ the Homoaldol Reaction with 1,3‐Chirality Transfer.

Abstract Deprotonation of the carbamate (Ib) [from (Ia)] and trapping of the intermediate Li species (II) with the aldehyde (IVa) yield the Z‐anti (IIIa) and the Z‐ syn (IIIb) adducts.

Bibliographic Details
Published in:Chemischer Informationsdienst
Main Authors: HOPPE, D., KRAEMER, T. +
Format: Article in Journal/Newspaper
Language:English
Published: Wiley 1986
Subjects:
Carbonic acid
Online Access:http://dx.doi.org/10.1002/chin.198622082
http://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fchin.198622082
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id crwiley:10.1002/chin.198622082
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spelling crwiley:10.1002/chin.198622082 2024-06-02T08:05:10+00:00 ChemInform Abstract: Metalated Nitrogen Derivatives of Carbonic Acid in Organic Synthesis. Part 31. α‐Deprotonation of an α‐Chiral 2‐Alkenylcarbamate with Retention and Lithium‐Titanium Exchange with Inversion ‐ the Homoaldol Reaction with 1,3‐Chirality Transfer. HOPPE, D. KRAEMER, T. + 1986 http://dx.doi.org/10.1002/chin.198622082 http://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fchin.198622082 https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fchin.198622082 https://onlinelibrary.wiley.com/doi/pdf/10.1002/chin.198622082 en eng Wiley http://onlinelibrary.wiley.com/termsAndConditions#vor Chemischer Informationsdienst volume 17, issue 22 ISSN 0009-2975 2199-2924 journal-article 1986 crwiley https://doi.org/10.1002/chin.198622082 2024-05-03T11:35:24Z Abstract Deprotonation of the carbamate (Ib) [from (Ia)] and trapping of the intermediate Li species (II) with the aldehyde (IVa) yield the Z‐anti (IIIa) and the Z‐ syn (IIIb) adducts. Article in Journal/Newspaper Carbonic acid Wiley Online Library Chemischer Informationsdienst 17 22
institution Open Polar
collection Wiley Online Library
op_collection_id crwiley
language English
description Abstract Deprotonation of the carbamate (Ib) [from (Ia)] and trapping of the intermediate Li species (II) with the aldehyde (IVa) yield the Z‐anti (IIIa) and the Z‐ syn (IIIb) adducts.
format Article in Journal/Newspaper
author HOPPE, D.
KRAEMER, T. +
spellingShingle HOPPE, D.
KRAEMER, T. +
ChemInform Abstract: Metalated Nitrogen Derivatives of Carbonic Acid in Organic Synthesis. Part 31. α‐Deprotonation of an α‐Chiral 2‐Alkenylcarbamate with Retention and Lithium‐Titanium Exchange with Inversion ‐ the Homoaldol Reaction with 1,3‐Chirality Transfer.
author_facet HOPPE, D.
KRAEMER, T. +
author_sort HOPPE, D.
title ChemInform Abstract: Metalated Nitrogen Derivatives of Carbonic Acid in Organic Synthesis. Part 31. α‐Deprotonation of an α‐Chiral 2‐Alkenylcarbamate with Retention and Lithium‐Titanium Exchange with Inversion ‐ the Homoaldol Reaction with 1,3‐Chirality Transfer.
title_short ChemInform Abstract: Metalated Nitrogen Derivatives of Carbonic Acid in Organic Synthesis. Part 31. α‐Deprotonation of an α‐Chiral 2‐Alkenylcarbamate with Retention and Lithium‐Titanium Exchange with Inversion ‐ the Homoaldol Reaction with 1,3‐Chirality Transfer.
title_full ChemInform Abstract: Metalated Nitrogen Derivatives of Carbonic Acid in Organic Synthesis. Part 31. α‐Deprotonation of an α‐Chiral 2‐Alkenylcarbamate with Retention and Lithium‐Titanium Exchange with Inversion ‐ the Homoaldol Reaction with 1,3‐Chirality Transfer.
title_fullStr ChemInform Abstract: Metalated Nitrogen Derivatives of Carbonic Acid in Organic Synthesis. Part 31. α‐Deprotonation of an α‐Chiral 2‐Alkenylcarbamate with Retention and Lithium‐Titanium Exchange with Inversion ‐ the Homoaldol Reaction with 1,3‐Chirality Transfer.
title_full_unstemmed ChemInform Abstract: Metalated Nitrogen Derivatives of Carbonic Acid in Organic Synthesis. Part 31. α‐Deprotonation of an α‐Chiral 2‐Alkenylcarbamate with Retention and Lithium‐Titanium Exchange with Inversion ‐ the Homoaldol Reaction with 1,3‐Chirality Transfer.
title_sort cheminform abstract: metalated nitrogen derivatives of carbonic acid in organic synthesis. part 31. α‐deprotonation of an α‐chiral 2‐alkenylcarbamate with retention and lithium‐titanium exchange with inversion ‐ the homoaldol reaction with 1,3‐chirality transfer.
publisher Wiley
publishDate 1986
url http://dx.doi.org/10.1002/chin.198622082
http://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fchin.198622082
https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fchin.198622082
https://onlinelibrary.wiley.com/doi/pdf/10.1002/chin.198622082
genre Carbonic acid
genre_facet Carbonic acid
op_source Chemischer Informationsdienst
volume 17, issue 22
ISSN 0009-2975 2199-2924
op_rights http://onlinelibrary.wiley.com/termsAndConditions#vor
op_doi https://doi.org/10.1002/chin.198622082
container_title Chemischer Informationsdienst
container_volume 17
container_issue 22
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