ChemInform Abstract: Metalated Nitrogen Derivatives of Carbonic Acid in Organic Synthesis. Part 31. α‐Deprotonation of an α‐Chiral 2‐Alkenylcarbamate with Retention and Lithium‐Titanium Exchange with Inversion ‐ the Homoaldol Reaction with 1,3‐Chirality Transfer.
Abstract Deprotonation of the carbamate (Ib) [from (Ia)] and trapping of the intermediate Li species (II) with the aldehyde (IVa) yield the Z‐anti (IIIa) and the Z‐ syn (IIIb) adducts.
| Published in: | Chemischer Informationsdienst |
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| Main Authors: | , |
| Format: | Article in Journal/Newspaper |
| Language: | English |
| Published: |
Wiley
1986
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| Subjects: | |
| Online Access: | http://dx.doi.org/10.1002/chin.198622082 http://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fchin.198622082 https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fchin.198622082 https://onlinelibrary.wiley.com/doi/pdf/10.1002/chin.198622082 |
| Summary: | Abstract Deprotonation of the carbamate (Ib) [from (Ia)] and trapping of the intermediate Li species (II) with the aldehyde (IVa) yield the Z‐anti (IIIa) and the Z‐ syn (IIIb) adducts. |
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