Molybdenum Carbide as Alternative Catalysts to Precious Metals for Highly Selective Reduction of CO 2 to CO

Abstract Rising atmospheric CO 2 is expected to have negative effects on the global environment from its role in climate change and ocean acidification. Utilizing CO 2 as a feedstock to make valuable chemicals is potentially more desirable than sequestration. A substantial reduction of CO 2 levels r...

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Bibliographic Details
Published in:Angewandte Chemie International Edition
Main Authors: Porosoff, Marc D., Yang, Xiaofang, Boscoboinik, J. Anibal, Chen, Jingguang G.
Format: Article in Journal/Newspaper
Language:English
Published: Wiley 2014
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Online Access:http://dx.doi.org/10.1002/anie.201404109
https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fanie.201404109
https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.201404109
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Summary:Abstract Rising atmospheric CO 2 is expected to have negative effects on the global environment from its role in climate change and ocean acidification. Utilizing CO 2 as a feedstock to make valuable chemicals is potentially more desirable than sequestration. A substantial reduction of CO 2 levels requires a large‐scale CO 2 catalytic conversion process, which in turn requires the discovery of low‐cost catalysts. Results from the current study demonstrate the feasibility of using the non‐precious metal material molybdenum carbide (Mo 2 C) as an active and selective catalyst for CO 2 conversion by H 2 .