Nonmonotonic Coupled Dissolution‐Precipitation Reactions at the Mineral–Water Interface

• Published in: Advanced Functional Materials
• Main Authors: Rao, Ashit, Ayirala, Subhash C., Alotaibi, Mohammed B., Duits, Michel H. G., Yousef, A. A., Mugele, Frieder
• Format: Article in Journal/Newspaper
• Language: English
• Published: Wiley 2021
• Subjects: Ocean acidification
• Online Access: http://dx.doi.org/10.1002/adfm.202106396; https://onlinelibrary.wiley.com/doi/pdf/10.1002/adfm.202106396; https://onlinelibrary.wiley.com/doi/full-xml/10.1002/adfm.202106396

Abstract Dissolution is inherent to fluid‐mineral systems. Yet its impact on minerals reacting with electrolytes is overlooked. Here, a novel nonmonotonic behavior for the surface interactions of carbonates (calcite and Mg‐calcite) with organic acids is reported. Applying a bioinspired approach, Mg‐calcite sensors via amorphous precursors, avoiding any preconditioning with functional groups are synthesized. A quartz crystal microbalance is used to study the mass changes of the mineral on contact with organic acids under varying ionic conditions, temperatures, and flow velocities. Supported by confocal Raman microscopy and potentiometric titrations, nonmonotonous mass developments are found as a function of Ca 2+ concentration and flowrate, and attributed to three coupled chemical reactions: i) carbonate dissolution via Ca 2+ ion complexation with organic molecules, and the formation of organo‐calcium compounds as ii) a surface phase at the mineral–water interface, and iii) particles in the bulk fluid. These processes depend on local ion contents and the precipitation onset (i.e., saturation index) of organo‐calcium salts, both of which substantially differ in the bulk fluid and in the fluid boundary layer at mineral interfaces. This continuum between dissolution and precipitation provides a conceptual framework to address reactions at mineral interfacial across disciplines including biomineralization, ocean acidification and reservoir geochemistry.