Chemistry in the Clouds: The Role of Aerosols in Atmospheric Chemistry

Ever since the discovery of the ozone hole over the Antarctic and the recognition of the damaging effects of acid rain, the role of atmospheric aerosol particles in determining the chemical balance of the atmosphere has received much attention. Aerosol particles produced in combustion can also have...

Full description

Bibliographic Details
Published in:Science Progress
Main Authors: Reid, Jonathan P., Sayer, Robert M.
Format: Article in Journal/Newspaper
Language:English
Published: SAGE Publications 2002
Subjects:
Online Access:http://dx.doi.org/10.3184/003685002783238807a
http://journals.sagepub.com/doi/pdf/10.3184/003685002783238807a
Description
Summary:Ever since the discovery of the ozone hole over the Antarctic and the recognition of the damaging effects of acid rain, the role of atmospheric aerosol particles in determining the chemical balance of the atmosphere has received much attention. Aerosol particles produced in combustion can also have a deleterious effect on human health. In this article we review the chemistry that can occur on aerosol particles, particularly on aqueous based aerosols in the troposphere. The sources, transformation and loss mechanisms of atmospheric aerosol will be discussed. In particular, we will focus on the role of chemical transformation on aerosol particles in promoting reactions that would otherwise be too slow in the homogeneous atmospheric gas phase. Heterogeneous reaction mechanisms of some key chemical reactions will be described. Recent observations of a high organic content of tropospheric aerosol particles will be described and a model of organic coated aerosols will be reviewed.