Chemo-enzymatic Baeyer–Villiger oxidation of 4-methylcyclohexanone via kinetic resolution of racemic carboxylic acids: direct access to enantioenriched lactone
A new method for the asymmetric chemo-enzymatic Baeyer–Villiger oxidation of 4-methylcyclohexanone to enantioenriched lactone in the presence of (±)-4-methyloctanoic acid, Candida Antarctica lipase B and 30% aq. H 2 O 2 has been developed.
| Published in: | Chemical Communications |
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| Main Authors: | , |
| Format: | Article in Journal/Newspaper |
| Language: | English |
| Published: |
Royal Society of Chemistry (RSC)
2016
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| Subjects: | |
| Online Access: | http://dx.doi.org/10.1039/c5cc08519e http://pubs.rsc.org/en/content/articlepdf/2016/CC/C5CC08519E |
| Summary: | A new method for the asymmetric chemo-enzymatic Baeyer–Villiger oxidation of 4-methylcyclohexanone to enantioenriched lactone in the presence of (±)-4-methyloctanoic acid, Candida Antarctica lipase B and 30% aq. H 2 O 2 has been developed. |
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