Formation of magnesium silicate hydrate cement in nature

Tillite lithified by magnesium silicate hydrate (M-S-H) cement has been formed at the surface of the Feragen Ultramafic Body in SE Norway. Serpentinization of olivine-rich rocks led to formation of brucite that dissolves during weathering to form a high pH (>9) Mg-rich fluid. This fluid disso...

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Bibliographic Details
Main Authors: de Ruiter, Lisa, Austrheim, Håkon
Format: Other/Unknown Material
Language:unknown
Published: California Digital Library (CDL) 2019
Subjects:
Online Access:http://dx.doi.org/10.31223/osf.io/5aqnz
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Summary:Tillite lithified by magnesium silicate hydrate (M-S-H) cement has been formed at the surface of the Feragen Ultramafic Body in SE Norway. Serpentinization of olivine-rich rocks led to formation of brucite that dissolves during weathering to form a high pH (>9) Mg-rich fluid. This fluid dissolves quartz deposited by glaciers during the Weichselian glaciation. Subsequent evaporation leads to the precipitation of a nanocrystalline magnesium silicate hydrate phase with the approximate composition Mg8Si8O20(OH)8·6H2O. The resulting cemented rock is characterized by disintegrated and partly dissolved quartz grains that are surrounded by the M-S-H cement. This process occurs at surface conditions in a subarctic climate and is known to take place on the timescale of a few decades, as constrained by mining activities. Magnesium-based cement is currently of high interest as the search for environmentally friendly cement is a pressing task considering that the widely used Portland cement accounts for about 7% of the worldwide anthropogenic CO2 emission. As this study provides new key insights into the formation process of natural CO2-neutral magnesium-based cement on the field- and microscale, it could contribute in the development of a new sustainable construction material.