Kohlensäurebis(trimethylsilyl)ester: Spektroskopische Charakterisierung und verbesserte Darstellung/ The Bis(trimethylsilyl)ester of Carbonic Acid: Spectroscopic Characterization and Improved Preparation

• Published in: Zeitschrift für Naturforschung B
• Main Authors: Minkwitz, Rolf, Schneider, Stefan
• Format: Article in Journal/Newspaper
• Language: English
• Published: Walter de Gruyter GmbH 1998
• Subjects: General Chemistry; Carbonic acid
• Online Access: http://dx.doi.org/10.1515/znb-1998-0812; https://www.degruyter.com/view/journals/znb/53/8/article-p849.xml; https://www.degruyter.com/document/doi/10.1515/znb-1998-0812/xml; https://www.degruyter.com/document/doi/10.1515/znb-1998-0812/pdf

Keywords The low temperature preparation of the bistrimethylsilylester of carbonic acid is reported. The hydrolysable and thermolabile (Me 3 SiO) 2 CO has been characterized by vibrational and NMR spectroscopic methods. Under inert conditions the (Me 3 SiO) 2 CO is stable at 233 K for several weeks.