Ein Beitrag zur Reaktivität des Monohydrazids von P 3 N 3 F 6 / A Contribution to the Reactivity of the Monohydrazide of P 3 N 3 F 6
P 3 N 3 F 5 NHNH 2 reacts with P 3 N 3 F 5 Br to yield the symmetric hydrazide P 3 N 3 F 5 -NHNHP 3 N 3 F 5 . Compounds of the type P 3 N 3 F 5 NHNHC(O)CX 3 and P 3 N 3 F 5 NHN = CX 2 are readily prepared from P 3 N 3 F 5 NHNH 2 and carbonic acid chlorides and respectively aldehydes and ketones. The...
Published in: | Zeitschrift für Naturforschung B |
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Main Authors: | , |
Format: | Article in Journal/Newspaper |
Language: | English |
Published: |
Walter de Gruyter GmbH
1974
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Subjects: | |
Online Access: | http://dx.doi.org/10.1515/znb-1974-3-409 https://www.degruyter.com/view/journals/znb/29/3-4/article-p177.xml https://www.degruyter.com/document/doi/10.1515/znb-1974-3-409/xml https://www.degruyter.com/document/doi/10.1515/znb-1974-3-409/pdf |
Summary: | P 3 N 3 F 5 NHNH 2 reacts with P 3 N 3 F 5 Br to yield the symmetric hydrazide P 3 N 3 F 5 -NHNHP 3 N 3 F 5 . Compounds of the type P 3 N 3 F 5 NHNHC(O)CX 3 and P 3 N 3 F 5 NHN = CX 2 are readily prepared from P 3 N 3 F 5 NHNH 2 and carbonic acid chlorides and respectively aldehydes and ketones. The reaction product of P 3 N 3 F 5 NHNH 2 and CH 3 CH 2 CHO gives a dimeric derivate. Its structure was proofed by molecular weight, IR- and mass spectra. |
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