Ein Beitrag zur Reaktivität des Monohydrazids von P 3 N 3 F 6 / A Contribution to the Reactivity of the Monohydrazide of P 3 N 3 F 6

P 3 N 3 F 5 NHNH 2 reacts with P 3 N 3 F 5 Br to yield the symmetric hydrazide P 3 N 3 F 5 -NHNHP 3 N 3 F 5 . Compounds of the type P 3 N 3 F 5 NHNHC(O)CX 3 and P 3 N 3 F 5 NHN = CX 2 are readily prepared from P 3 N 3 F 5 NHNH 2 and carbonic acid chlorides and respectively aldehydes and ketones. The...

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Bibliographic Details
Published in:Zeitschrift für Naturforschung B
Main Authors: Roesky, Herbert W., Janssen, Enno
Format: Article in Journal/Newspaper
Language:English
Published: Walter de Gruyter GmbH 1974
Subjects:
General Chemistry
Carbonic acid
Online Access:http://dx.doi.org/10.1515/znb-1974-3-409
https://www.degruyter.com/view/journals/znb/29/3-4/article-p177.xml
https://www.degruyter.com/document/doi/10.1515/znb-1974-3-409/xml
https://www.degruyter.com/document/doi/10.1515/znb-1974-3-409/pdf
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Summary:P 3 N 3 F 5 NHNH 2 reacts with P 3 N 3 F 5 Br to yield the symmetric hydrazide P 3 N 3 F 5 -NHNHP 3 N 3 F 5 . Compounds of the type P 3 N 3 F 5 NHNHC(O)CX 3 and P 3 N 3 F 5 NHN = CX 2 are readily prepared from P 3 N 3 F 5 NHNH 2 and carbonic acid chlorides and respectively aldehydes and ketones. The reaction product of P 3 N 3 F 5 NHNH 2 and CH 3 CH 2 CHO gives a dimeric derivate. Its structure was proofed by molecular weight, IR- and mass spectra.

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