Inelastic Neutron Scattering from Ice and Other Proton-containing Substances

Abstract A brief introduction to neutron scattering is given with special emphasis on the difference between coherent and incoherent contributions. The following report of recent work on ice contains the determination and verification of some phonon dispersion curves, and outlines the state of the a...

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Bibliographic Details
Published in:Journal of Glaciology
Main Author: Dorner, Bruno
Format: Article in Journal/Newspaper
Language:English
Published: Cambridge University Press (CUP) 1978
Subjects:
Online Access:http://dx.doi.org/10.1017/s0022143000033438
https://www.cambridge.org/core/services/aop-cambridge-core/content/view/S0022143000033438
Description
Summary:Abstract A brief introduction to neutron scattering is given with special emphasis on the difference between coherent and incoherent contributions. The following report of recent work on ice contains the determination and verification of some phonon dispersion curves, and outlines the state of the art on diffuse scattering due to the proton disorder. Results on “two-dimensional ice” in copper formate tetrahydrate are of great interest as this system exhibits a phase transformation below which the protons are ordered. The study of rotational diffusion and of the tunnel splitting of the rotational ground state of molecules which contain protons is discussed in some detail. These investigations are now possible with very high energy resolution ΔE ≈ 5 × 10 -8 eV (4 • 10-4 cm- 1 or 12 MHz).