SN2 reactions
This dataset probes chemical reactions of methyl halides with halide anions, i.e. X- + CH3Y -> CH3X + Y-, and contains structures for all possible combinations of X,Y = F, Cl, Br, I. The dataset also includes various structures for several smaller molecules that can be formed in fragmentation rea...
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ftzenodo:oai:zenodo.org:2605341 2023-05-15T17:53:50+02:00 SN2 reactions Unke, Oliver Thorsten Meuwly, Markus 2019-03-25 https://zenodo.org/record/2605341 https://doi.org/10.5281/zenodo.2605341 unknown arxiv:arXiv:1902.08408 doi:10.5281/zenodo.2605340 https://zenodo.org/record/2605341 https://doi.org/10.5281/zenodo.2605341 oai:zenodo.org:2605341 info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by/4.0/legalcode SN2 reactions quantum chemistry density functional theory DFT info:eu-repo/semantics/other dataset 2019 ftzenodo https://doi.org/10.5281/zenodo.260534110.5281/zenodo.2605340 2023-03-11T03:46:53Z This dataset probes chemical reactions of methyl halides with halide anions, i.e. X- + CH3Y -> CH3X + Y-, and contains structures for all possible combinations of X,Y = F, Cl, Br, I. The dataset also includes various structures for several smaller molecules that can be formed in fragmentation reactions, such as CH3X, HX, CHX or CH2X- as well as geometries for H2, CH2, CH3+ and XY interhalogen compounds. In total, the dataset provides reference energies, forces, and dipole moments for 452709 structures calculated at the DSD-BLYP-D3(BJ)/def2-TZVP level of theory [1-4] using the ORCA 4.0.1 code [5,6]. For more details, see https://arxiv.org/abs/1902.08408. [1] Grimme, S.; Antony, J.; Ehrlich, S. and Krieg, H. J. Chem. Phys. 132, 154104 (2010). [2] Kozuch, S.; Gruzman, D. and Martin, J. M. J. Phys. Chem. C 114, 20801-20808 (2010). [3] Grimme, S.; Ehrlich, S. and Goerigk, L. J. Comput. Chem. 32, 1456-1465 (2011). [4] Weigend, F. and Ahlrichs, R. Phys. Chem. Chem. Phys. 7, 3297-3305 (2005). [5] Neese, F. Wiley Interdiscip. Rev. Comput. Mol. Sci. 2, 73-78 (2012). [6] Neese, F. Wiley Interdiscip. Rev. Comput. Mol. Sci. 8, e1327 (2018). Dataset Orca Zenodo |
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SN2 reactions quantum chemistry density functional theory DFT |
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SN2 reactions quantum chemistry density functional theory DFT Unke, Oliver Thorsten Meuwly, Markus SN2 reactions |
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SN2 reactions quantum chemistry density functional theory DFT |
description |
This dataset probes chemical reactions of methyl halides with halide anions, i.e. X- + CH3Y -> CH3X + Y-, and contains structures for all possible combinations of X,Y = F, Cl, Br, I. The dataset also includes various structures for several smaller molecules that can be formed in fragmentation reactions, such as CH3X, HX, CHX or CH2X- as well as geometries for H2, CH2, CH3+ and XY interhalogen compounds. In total, the dataset provides reference energies, forces, and dipole moments for 452709 structures calculated at the DSD-BLYP-D3(BJ)/def2-TZVP level of theory [1-4] using the ORCA 4.0.1 code [5,6]. For more details, see https://arxiv.org/abs/1902.08408. [1] Grimme, S.; Antony, J.; Ehrlich, S. and Krieg, H. J. Chem. Phys. 132, 154104 (2010). [2] Kozuch, S.; Gruzman, D. and Martin, J. M. J. Phys. Chem. C 114, 20801-20808 (2010). [3] Grimme, S.; Ehrlich, S. and Goerigk, L. J. Comput. Chem. 32, 1456-1465 (2011). [4] Weigend, F. and Ahlrichs, R. Phys. Chem. Chem. Phys. 7, 3297-3305 (2005). [5] Neese, F. Wiley Interdiscip. Rev. Comput. Mol. Sci. 2, 73-78 (2012). [6] Neese, F. Wiley Interdiscip. Rev. Comput. Mol. Sci. 8, e1327 (2018). |
format |
Dataset |
author |
Unke, Oliver Thorsten Meuwly, Markus |
author_facet |
Unke, Oliver Thorsten Meuwly, Markus |
author_sort |
Unke, Oliver Thorsten |
title |
SN2 reactions |
title_short |
SN2 reactions |
title_full |
SN2 reactions |
title_fullStr |
SN2 reactions |
title_full_unstemmed |
SN2 reactions |
title_sort |
sn2 reactions |
publishDate |
2019 |
url |
https://zenodo.org/record/2605341 https://doi.org/10.5281/zenodo.2605341 |
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Orca |
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Orca |
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arxiv:arXiv:1902.08408 doi:10.5281/zenodo.2605340 https://zenodo.org/record/2605341 https://doi.org/10.5281/zenodo.2605341 oai:zenodo.org:2605341 |
op_rights |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by/4.0/legalcode |
op_doi |
https://doi.org/10.5281/zenodo.260534110.5281/zenodo.2605340 |
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1766161540498587648 |