�씤媛�, 臾쇨컻, �옱媛덈ℓ湲� �븣�뿉�꽌 諛쒓껄�릺�뒗 PBDE�쓽 �냽�룄蹂��솕�뿉 ���븳 怨좎같�뿰援�

• Other Authors: Jung, Hwan Sug
• Format: Thesis
• Language: unknown
• Published: �뿰�꽭���븰援� 蹂닿굔���븰�썝 2004
• Subjects: Arctic
• Online Access: https://ir.ymlib.yonsei.ac.kr/handle/22282913/135998

�솚寃쎈낫嫄댄븰怨�/�꽍�궗 [�븳湲�]Polybrominated diphenyl ethers (PBDEs)�뒗 �솕�옱 諛쒖깮�쓣 吏��뿰 �떆�궎�뒗 �궃�뿰�옱濡쒖꽌 而댄벂�꽣, �뀛�젅鍮꾩쟾�쓣 鍮꾨’�븳 �쟾�옄�젣�뭹, 移댄럹�듃, 媛�援�, 吏곷Ъ �벑 �떎�뼇�븳 遺꾩빞�뿉�꽌 �궗�슜�릺怨� �엳�떎. �궃�뿰�옱濡쒖꽌�쓽 �쑀�슜�꽦�뿉�룄 遺덇뎄�븯怨� PBDEs�뒗 polychlorinated biphenyls (PCB)�굹 dichloro-diphenyl-trichloroethane (DDT)�� �쑀�궗�븳 �떊寃쏀븰�쟻 利앹긽 肉� �븘�땲�씪, 媛묒긽�꽑 �샇瑜대が�쓣 鍮꾨’�븳 �뿬�윭 �궡遺꾨퉬怨꾩뿉 �씠�긽�쓣 �씪�쑝�궓�떎怨� �븣�젮�졇 �엳�떎. PBDEs 以� �쟾 �꽭怨꾩쟻�쑝濡� penta-BDE, octa-BDE, deca-BDE媛� 二쇰줈 �긽�뾽�쟻�쑝濡� �깮�궛�릺硫�, 洹� �깮�궛�웾�뒗 媛곴컖 14%, 6%, 80%瑜� 李⑥��븯怨� �엳�떎. �씠�뱾 以� �듅�엳 penta-BDE�� octa-BDE媛� �깮臾쇱껜�뿉 異뺤쟻�맂�떎怨� �븣�젮�졇 �엳�쑝硫�, �뿬�윭 �뿰援ъ뿉�꽌 �깮臾쇱껜�뿉 PBDEs媛� 異뺤쟻�맂 �젙�룄瑜� 寃�異쒗븯���떎. 蹂� 怨좎같 �끉臾몄뿉�꽌�뒗 PBDEs congeners 以�, 媛��옣 �쓷�엳 寃�異쒕릺�뒗 BDE-47, BDE-99, BDE-100, BDE-153, BDE-154�쓽 寃�異쒕웾�쓣 媛곴린 �떎瑜� �꽌�떇 �솚寃쎌뿉 �궡怨� �엳�뒗 �뒪�썾�뜶 �뿬�꽦�쓽 紐⑥쑀, 遺곴레�빐 臾쇨컻�쓽 吏�諛� 議곗쭅, �삤���샇 �뿰�븞�쓽 �옱媛덈ℓ湲곗븣�뿉 �뵲�씪 鍮꾧탳�븯�뿬, 洹몃뱾�쓽 �깮�솢�솚寃쎌뿉 �뵲�씪 PBDEs 異뺤쟻�웾�씠 �뼱�뼚�븳吏� 怨좎같�븯���떎. �삉�븳, 媛곴컖�쓽 congener�쓽 蹂��솕�웾�쓣 �떆媛꾩뿉 �뵲�씪 異붿쟻愿�李고븯�뿬, 洹� �옄猷뚮줈 penta-BDE�� octa-BDE�쓽 �뼇�쓣 異붿젙�븯�뿬 洹� 蹂��솕 異붿씠瑜� 愿�李고븯���떎. �뒪�썾�뜶 �뿬�꽦�쓽 紐⑥쑀�뿉�꽌 寃�異쒕맂 �쟾泥� PBDEs�쓽 �뼇�� 1972�뀈遺��꽣 1990�뀈 �� �썑諛섍퉴吏� 怨꾩냽 利앷��븯�떎媛�, 1990�뀈�� �썑諛� �떎�떆 媛먯냼�븯���떎. �씠�윭�븳 媛먯냼異붿꽭濡쒖쓽 蹂��솕�뒗 �쑀�읇 吏��뿭�뿉�꽌�쓽 penta-BDE�뿉 ���븳 洹쒖젣媛� 媛��옣 �겙 �옉�슜�쓣 �븯���쑝由щ씪 蹂몃떎. PBDEs 以� BDE-47�씠 媛��옣 留롮씠 寃�異쒕릺�뿀�쑝硫�, penta-BDE 異붿젙�웾�룄 �룊洹� 86.5%瑜� 李⑥��븯�뿬, �뒪�썾�뜶 �뿬�꽦�쓽 �삤�뿼�썝�쑝濡쒖꽌 penta-BDE�쓽 �뿭�븷�씠 而몃떎. 遺곴레�빐 臾쇨컻�쓽 吏�諛⑹“吏곸뿉�꽌 寃�異쒕맂 PBDEs�쓽 �뼇�룄 1980�뀈 �씠�썑 怨꾩냽 利앷��븯���쑝硫�, 洹� 寃�異쒕웾�� 1990�뀈�� �썑諛섏씠 �릺�뼱�룄 媛먯냼�븯吏� �븡�븯�떎. �씠�뒗 遺곷�몄��뿭�� penta-BDE�쓽 二� �깮�궛吏��씠濡�, penta-BDE�쓽 �깮�궛�뿉 ���븳 洹쒖젣媛� �엳吏� �븡�븘, �씠寃껋씠 �뿬由꾩쿋 洹뱀�諛⑹쑝濡� �쑀�엯�릺�뒗 ��湲곕�� �넻�빐 遺곴레�빐 臾쇨컻�뿉 異뺤쟻�릺�뿀�쑝由щ씪 異붿젙�맂�떎. 遺곴레�빐 臾쇨컻�뿉�꽌�룄 PBDEs 以� BDE-47�씠 媛��옣 留롮씠 寃�異쒕릺�뿀�쑝硫�, �씠�뒗 �떎瑜� �씤媛꾩씠�굹 �떎瑜� �깮臾쇱쭛�떒�뿉�꽌蹂대떎 �듅�엳 �뜑 留롮씠 寃�異쒕릺�뿀�떎. �삉�븳 penta-BDE �뿭�떆 �떎瑜� �깮臾쇱쭛�떒�뿉�꽌蹂대떎 留롮씠 寃�異쒕릺�뿀�떎. 2000�뀈 �삤���샇 �뿰�븞�쓽 �옱媛덈ℓ湲� �븣�뿉�꽌 寃�異쒕맂 �븷濡쒓쾺 �썝�냼瑜� �븿�쑀�븳 �쑀湲고솕�빀臾� 以� PBDEs�뒗 PCD�� DDE�뿉 �씠�뼱 �꽭 踰덉㎏濡� 媛��옣 留롮씠 寃�異쒕릺�뒗 �쑀湲고솕�빀臾쇱씠���쑝硫�, 洹� �냽�룄�룄 1981�뀈 9.4 g/g�뿉�꽌 2000�뀈 530 g/g �쑝濡� �빟 56諛� 利앷��븯���떎. �씠�윭�븳 利앷��룺�� 二쇰줈 BDE-47, BDE-100, BDE-99�쓽 利앷��뿉 �쓽�븳 寃껋씠硫�, �씠以� BDE-47�씠 媛��옣 �겙 鍮꾩쨷�쓣 李⑥��븯���떎. �씤媛꾧낵 �룞臾쇱뿉 ���븳 PBDEs�쓽 �깮臾� �궡 異뺤쟻�웾�� 1980�뀈 �씠�썑 怨꾩냽 利앷� 異붿꽭瑜� �굹���깉�쑝硫�, �씪遺� �깮臾� 吏묐떒�뿉�꽌�뒗 1990�뀈�� �썑諛� 媛먯냼�븯湲곕룄 �븯���떎. �씠�윭�븳 PBDEs�쓽 �깮臾� �궡 異뺤쟻�웾�� �꽌�떇 �솚寃� 二쇰��쓽 PBDEs�쓽 �냼鍮꾨웾怨� 愿�怨꾧� �엳�뼱, penta-BDE�쓽 二� �냼鍮꾩��씤 遺곷�� 吏��뿭�쓽 �쁺�뼢沅뚯뿉 �넃�씤 �깮臾쇨뎔�뿉�꽌�뒗 洹� 媛먯냼異붿꽭媛� �몦�솕�릺�뼱 �엳�뿀�떎. �뿬�윭 �깮臾쇱뿉�꽌 諛쒓껄�릺�뒗 怨듯넻�쟻�쑝濡� 媛��옣 �쓷�븳 �삎�깭�뒗 BDE-47�씠���쑝硫�, �씠�뒗 �듅�엳 遺곷�� 吏��뿭�쓽 �쁺�뼢沅뚯뿉 �넃�씤 遺곴레�빐 臾쇨컻�쓽 吏�諛� 議곗쭅�뿉�꽌 �넂�� 鍮꾩쑉濡� 寃�異쒕릺�뿀�떎. �쟾泥� PBDEs 以� penta-BDE媛� 李⑥��븯�뒗 鍮꾩쑉�룄 �쟻寃뚮뒗 66.0%�뿉�꽌 理쒓퀬 98.8%濡� penta-BDE媛� �깮臾� �궡�뿉 異뺤쟻�릺�뒗 二� PBDEs���떎. penta-BDE 以� BDE-47�씠 BDE-99蹂대떎 �뜑 留롮씠 異뺤쟻�릺�뿀�쑝硫�, �씠�뒗 BDE-47怨� BDE-99�씠 �깮臾� �궡�뿉�꽌 鍮꾩듂�븳 諛섍컧湲곕�� 媛�吏꾨떎�븯�뜑�씪�룄, �깮臾� �궡�뿉�꽌�쓽 �씠�룞 諛⑹떇�쓽 李⑥씠, polymer matrix瑜� �넻怨쇳븯�뒗 �젙�룄, �궙�� 湲고솕�젏�쑝濡� �씤�븳 鍮좊Ⅸ �쟾�뙆 �벑 �뿬�윭 媛�吏� �슂�씤�씠 愿��뿬�븷 寃껋쑝濡� 異붿젙�맂�떎. �빑�떖�뼱 : Polybrominated diphenyl ethers (PBDEs), �궃�뿰�옱, penta-BDE, [�쁺臾�]Polybrominated diphenyl ethers (PBDEs) are flame retardants used in a wide range of materials such as television sets, computers, radios, textiles, and furniture. They appear to have an environmental dispersion simlar to that of polychlorinated biphenyls (PCBs) and chlorodiphenyltrichloroethane (DDT). In addition, based on its chemical structure and biological experiments, it is concerned that PBDE may have endotoxic or neurotoxic effects. Three commercial mixtures are widely used (penta-BDE, octa-BDE, and deca-BDE), making up 14%, 6%, and 80%. In contrast to deca-BDE, penta and octa-BDE are founded in both human and wildlifes. This paper is review of the available PBDE concentration founded in Swedish woman milk, Canadian arctic seal fat tissue, Great Lake gull eggs. PBDEs concentration has been increased in Swedish human milk, seals fat tissue, gull eggs from 1980. Most of the dramatic increases in total PBDEs concentraions observed over the past 20 years seem to be connected with the penta-BDE formulation, which is mainly used as a flame retardnat in North America. In 1997, PBDEs founded in Swedish woman milk have been decreased. It may be due to the restriction of the use of PBDEs in Europe. In PBDEs congener, BDE-47 was relatively higher in the all wildlifes. The concentration of BDE-47 measured in several wildlifes was varied from 66.0% to 98.8%. The concentration was highest in Canadian arctic seals which is influenced by North America. It may due to its relatively higher vapor pressure, or it may be due to the selective environmental elimination of BDE-47. Keywords : Polybrominated diphenyl ethers (PBDEs), Flame retardant, penta-BDE, octa-BDE open