Community-wide intercomparison exercise for the determination of dissolved iron in seawater
Author Posting. © The Authors, 2005. This is the author's version of the work. It is posted here by permission of Elsevier B. V. for personal use, not for redistribution. The definitive version was published in Marine Chemistry 98 (2006): 81-99, doi:10.1016/j.marchem.2005.07.002. The first larg...
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ftwhoas:oai:darchive.mblwhoilibrary.org:1912/566 2023-05-15T18:21:17+02:00 Community-wide intercomparison exercise for the determination of dissolved iron in seawater Bowie, Andrew R. Achterberg, Eric P. Croot, Peter L. Baar, Hein J. W. de Laan, Patrick Moffett, James W. Ussher, Simon J. Worsfold, Paul J. 2005-07-29 53444 bytes 266863 bytes application/pdf https://hdl.handle.net/1912/566 en_US eng https://doi.org/10.1016/j.marchem.2005.07.002 https://hdl.handle.net/1912/566 Iron Seawater Determination Intercomparison IRONAGES Large volume sample Preprint 2005 ftwhoas https://doi.org/10.1016/j.marchem.2005.07.002 2022-05-28T22:56:54Z Author Posting. © The Authors, 2005. This is the author's version of the work. It is posted here by permission of Elsevier B. V. for personal use, not for redistribution. The definitive version was published in Marine Chemistry 98 (2006): 81-99, doi:10.1016/j.marchem.2005.07.002. The first large-scale international intercomparison of analytical methods for the determination of dissolved iron in seawater was carried out between October 2000 and December 2002. The exercise was conducted as a rigorously “blind” comparison of 7 analytical techniques by 24 international laboratories. The comparison was based on a large volume (700 L), filtered surface seawater sample collected from the South Atlantic Ocean (the “IRONAGES” sample), which was acidified, mixed and bottled at sea. Two 1 L sample bottles were sent to each participant. Integrity and blindness were achieved by having the experiment designed and carried out by a small team, and overseen by an independent data manager. Storage, homogeneity and time-series stability experiments conducted over 2.5 years showed that interbottle variability of the IRONAGES sample was good (<7%), although there was a decrease in iron concentration in the bottles over time (from 0.8-0.5 nM) before a stable value was observed. This raises questions over the suitability of sample acidification and storage. For the complete dataset of 45 results (after excluding 3 outliers not passing the screening criteria), the mean concentration of dissolved iron in the IRONAGES sample was 0.59±0.21 nM, representing a coefficient of variation (%CV) for analytical comparability (“community precision”) of 36% (1s), a significant improvement over earlier exercises. Within-run precision (5-10%), inter-run precision (15%) and inter-bottle homogeneity (<7%) were much better than overall analytical comparability, implying the presence of: (1) random variability (inherent to all intercomparison exercises); (2) errors in quantification of the analytical blank; and (3) systematic inter-method ... Report South Atlantic Ocean Woods Hole Scientific Community: WHOAS (Woods Hole Open Access Server) Marine Chemistry 98 1 81 99 |
institution |
Open Polar |
collection |
Woods Hole Scientific Community: WHOAS (Woods Hole Open Access Server) |
op_collection_id |
ftwhoas |
language |
English |
topic |
Iron Seawater Determination Intercomparison IRONAGES Large volume sample |
spellingShingle |
Iron Seawater Determination Intercomparison IRONAGES Large volume sample Bowie, Andrew R. Achterberg, Eric P. Croot, Peter L. Baar, Hein J. W. de Laan, Patrick Moffett, James W. Ussher, Simon J. Worsfold, Paul J. Community-wide intercomparison exercise for the determination of dissolved iron in seawater |
topic_facet |
Iron Seawater Determination Intercomparison IRONAGES Large volume sample |
description |
Author Posting. © The Authors, 2005. This is the author's version of the work. It is posted here by permission of Elsevier B. V. for personal use, not for redistribution. The definitive version was published in Marine Chemistry 98 (2006): 81-99, doi:10.1016/j.marchem.2005.07.002. The first large-scale international intercomparison of analytical methods for the determination of dissolved iron in seawater was carried out between October 2000 and December 2002. The exercise was conducted as a rigorously “blind” comparison of 7 analytical techniques by 24 international laboratories. The comparison was based on a large volume (700 L), filtered surface seawater sample collected from the South Atlantic Ocean (the “IRONAGES” sample), which was acidified, mixed and bottled at sea. Two 1 L sample bottles were sent to each participant. Integrity and blindness were achieved by having the experiment designed and carried out by a small team, and overseen by an independent data manager. Storage, homogeneity and time-series stability experiments conducted over 2.5 years showed that interbottle variability of the IRONAGES sample was good (<7%), although there was a decrease in iron concentration in the bottles over time (from 0.8-0.5 nM) before a stable value was observed. This raises questions over the suitability of sample acidification and storage. For the complete dataset of 45 results (after excluding 3 outliers not passing the screening criteria), the mean concentration of dissolved iron in the IRONAGES sample was 0.59±0.21 nM, representing a coefficient of variation (%CV) for analytical comparability (“community precision”) of 36% (1s), a significant improvement over earlier exercises. Within-run precision (5-10%), inter-run precision (15%) and inter-bottle homogeneity (<7%) were much better than overall analytical comparability, implying the presence of: (1) random variability (inherent to all intercomparison exercises); (2) errors in quantification of the analytical blank; and (3) systematic inter-method ... |
format |
Report |
author |
Bowie, Andrew R. Achterberg, Eric P. Croot, Peter L. Baar, Hein J. W. de Laan, Patrick Moffett, James W. Ussher, Simon J. Worsfold, Paul J. |
author_facet |
Bowie, Andrew R. Achterberg, Eric P. Croot, Peter L. Baar, Hein J. W. de Laan, Patrick Moffett, James W. Ussher, Simon J. Worsfold, Paul J. |
author_sort |
Bowie, Andrew R. |
title |
Community-wide intercomparison exercise for the determination of dissolved iron in seawater |
title_short |
Community-wide intercomparison exercise for the determination of dissolved iron in seawater |
title_full |
Community-wide intercomparison exercise for the determination of dissolved iron in seawater |
title_fullStr |
Community-wide intercomparison exercise for the determination of dissolved iron in seawater |
title_full_unstemmed |
Community-wide intercomparison exercise for the determination of dissolved iron in seawater |
title_sort |
community-wide intercomparison exercise for the determination of dissolved iron in seawater |
publishDate |
2005 |
url |
https://hdl.handle.net/1912/566 |
genre |
South Atlantic Ocean |
genre_facet |
South Atlantic Ocean |
op_relation |
https://doi.org/10.1016/j.marchem.2005.07.002 https://hdl.handle.net/1912/566 |
op_doi |
https://doi.org/10.1016/j.marchem.2005.07.002 |
container_title |
Marine Chemistry |
container_volume |
98 |
container_issue |
1 |
container_start_page |
81 |
op_container_end_page |
99 |
_version_ |
1766200462642511872 |