Test of potential mass to charge 30 interferences from O2

Dataset: mz_30_int_from_o2 Molecular oxygen (O2) has been documented to ionize partially to NO+ in mass spectrometer sources, generating a signal that overlaps with that of 15N2 (mass-to-charge of 30). Here, we tested whether O2 needs to be specifically removed from the sample streams of the Membran...

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Main Authors: Granger, Julie, Bourbonnais, Annie, Wilson, Samuel
Format: Dataset
Language:English
Published: Biological and Chemical Oceanography Data Management Office (BCO-DMO). Contact: bco-dmo-data@whoi.edu 2019
Subjects:
Online Access:https://hdl.handle.net/1912/25119
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spelling ftwhoas:oai:darchive.mblwhoilibrary.org:1912/25119 2023-05-15T17:32:12+02:00 Test of potential mass to charge 30 interferences from O2 Granger, Julie Bourbonnais, Annie Wilson, Samuel North Atlantic Ocean, Pacific Ocean 2019-10-02 https://hdl.handle.net/1912/25119 en_US eng Biological and Chemical Oceanography Data Management Office (BCO-DMO). Contact: bco-dmo-data@whoi.edu https://lod.bco-dmo.org/id/dataset/778083 https://hdl.handle.net/1912/25119 doi:10.1575/1912/bco-dmo.778083.1 Creative Commons Attribution 4.0 https://creativecommons.org/licenses/by/4.0/ CC-BY doi:10.1575/1912/bco-dmo.778083.1 Dataset 2019 ftwhoas https://doi.org/10.1575/1912/bco-dmo.778083.1 2022-05-28T23:03:26Z Dataset: mz_30_int_from_o2 Molecular oxygen (O2) has been documented to ionize partially to NO+ in mass spectrometer sources, generating a signal that overlaps with that of 15N2 (mass-to-charge of 30). Here, we tested whether O2 needs to be specifically removed from the sample streams of the Membrane Inlet Mass Spectrometer and the Isotope Ratio Mass Spectrometer in order to properly quantitate 15N2 atom% at pertinent concentrations. Sample streams with and without O2 yielded similar signals, suggesting that O2 does not interfere with the 15N2 atom% measurements in the experimental range with the given instruments. For a complete list of measurements, refer to the full dataset description in the supplemental file 'Dataset_description.pdf'. The most current version of this dataset is available at: https://www.bco-dmo.org/dataset/778083 NSF Division of Ocean Sciences (NSF OCE) OCE-1732246 Dataset North Atlantic Woods Hole Scientific Community: WHOAS (Woods Hole Open Access Server) Pacific
institution Open Polar
collection Woods Hole Scientific Community: WHOAS (Woods Hole Open Access Server)
op_collection_id ftwhoas
language English
description Dataset: mz_30_int_from_o2 Molecular oxygen (O2) has been documented to ionize partially to NO+ in mass spectrometer sources, generating a signal that overlaps with that of 15N2 (mass-to-charge of 30). Here, we tested whether O2 needs to be specifically removed from the sample streams of the Membrane Inlet Mass Spectrometer and the Isotope Ratio Mass Spectrometer in order to properly quantitate 15N2 atom% at pertinent concentrations. Sample streams with and without O2 yielded similar signals, suggesting that O2 does not interfere with the 15N2 atom% measurements in the experimental range with the given instruments. For a complete list of measurements, refer to the full dataset description in the supplemental file 'Dataset_description.pdf'. The most current version of this dataset is available at: https://www.bco-dmo.org/dataset/778083 NSF Division of Ocean Sciences (NSF OCE) OCE-1732246
format Dataset
author Granger, Julie
Bourbonnais, Annie
Wilson, Samuel
spellingShingle Granger, Julie
Bourbonnais, Annie
Wilson, Samuel
Test of potential mass to charge 30 interferences from O2
author_facet Granger, Julie
Bourbonnais, Annie
Wilson, Samuel
author_sort Granger, Julie
title Test of potential mass to charge 30 interferences from O2
title_short Test of potential mass to charge 30 interferences from O2
title_full Test of potential mass to charge 30 interferences from O2
title_fullStr Test of potential mass to charge 30 interferences from O2
title_full_unstemmed Test of potential mass to charge 30 interferences from O2
title_sort test of potential mass to charge 30 interferences from o2
publisher Biological and Chemical Oceanography Data Management Office (BCO-DMO). Contact: bco-dmo-data@whoi.edu
publishDate 2019
url https://hdl.handle.net/1912/25119
op_coverage North Atlantic Ocean, Pacific Ocean
geographic Pacific
geographic_facet Pacific
genre North Atlantic
genre_facet North Atlantic
op_source doi:10.1575/1912/bco-dmo.778083.1
op_relation https://lod.bco-dmo.org/id/dataset/778083
https://hdl.handle.net/1912/25119
doi:10.1575/1912/bco-dmo.778083.1
op_rights Creative Commons Attribution 4.0
https://creativecommons.org/licenses/by/4.0/
op_rightsnorm CC-BY
op_doi https://doi.org/10.1575/1912/bco-dmo.778083.1
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